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Register a new userWater and Methanol Ice in L1544
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Miwa Goto
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Methanol and complex organic molecules have been found in cold starless cores, where a standard warm-up scenario would not work because of the absence of heat sources. A recent chemical model attributed the presence of methanol and large organics to the efficient chemical desorption and a class of neutral-neutral reactions that proceed fast at low temperatures in the gas phase. The model calls for a high abundance of methanol ice at the edge of the CO freeze-out zone in cold cloud cores. We performed medium resolution spectroscopy toward 3 field stars behind the starless core L1544 at 3 $mu$m to constrain the methanol ice abundance and compare it with the model predictions. One of the field stars shows a methanol-ice abundance of 11% with respect to water ice. This is higher than the typical methanol abundance previously found in cold cloud cores (4%), but is 4.5 times smaller than predicted. The reason for the disagreement between the observations and the model calculations is not yet understood.
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Water in outflows from protostars originates either as a result of gas-phase synthesis from atomic oxygen at T > 200 K, or from sputtered ice mantles containing water ice. We aim to quantify the contribution of the two mechanisms that lead to water in outflows, by comparing observations of gas-phase water to methanol (a grain surface product) towards three low-mass protostars in NGC1333. In doing so, we also quantify the amount of methanol destroyed in outflows. To do this, we make use of JCMT and Herschel-HIFI data of H2O, CH3OH and CO emission lines and compare them to RADEX non-LTE excitation simulations. We find up to one order of magnitude decrease in the column density ratio of CH3OH over H2O as the velocity increases in the line wings up to ~15 km/s. An independent decrease in X(CH3OH) with respect to CO of up to one order of magnitude is also found in these objects. We conclude that gas-phase formation of H2O must be active at high velocities (above 10 km/s, relative to the source velocity) to re-form the water destroyed during sputtering. In addition, the transition from sputtered water at low velocities to formed water at high velocities must be gradual. We place an upper limit of two orders of magnitude on the destruction of methanol by sputtering effects.
In interstellar clouds the deposition of water ice onto grains only occurs at visual extinctions above some threshold value A_th. At extinctions greater than A_th there is a (near-linear) correlation between the inferred column density of the water ice and A_V. For individual cloud complexes such as Taurus, Serpens and Rho-Ophiuchi, A_th and the gradients of the correlation are very similar along all lines of sight. We have investigated the origin of this phenomenon, with careful consideration of the various possible mechanisms that may be involved and have applied a full chemical model to analyse the behaviours and sensitivities in quiescent molecular clouds. Our key results are: (i) the ubiquity of the phenomenon points to a common cause, so that the lines of sight probe regions with similar, advanced, chemical and dynamical evolution, (ii) for Taurus and Serpens; A_th and the slope of the correlation can be explained as resulting from the balance of freeze-out of oxygen atoms and photodesorption of H2O molecules. No other mechanism can satisfactorily explain the phenomenon, (iii) A_th depends on the local density, suggesting that there is a correlation between local volume density and column density, (iv) the different values of A_th for Taurus and Serpens are probably due to variations in the local mean radiation field strength, (v) most ice is accreted onto grains that are initially very small (<0.01 microns), and (vi) the very high value of A_th observed in Rho-Ophiuchi cannot be explained in the same way, unless there is complex microstructure and/or a modification to the extinction characteristics.
We present the results of unbiased 22 GHz H2O water and 44 GHz class I CH3OH methanol maser surveys in the central 7x10 arcmin area of NGC 1333 and two additional mapping observations of a 22 GHz water maser in a ~3x3arcmin area of the IRAS4A region. In the 22 GHz water maser survey of NGC 1333 with sensitivity of sigma~0.3Jy, we confirmed masers toward H2O(B) in the region of HH 7-11 and IRAS4B. We also detected new water masers at ~20arcsec away in the western direction of IRAS4B or ~25arcsec away in the southern direction of IRAS4A. We could not however find young stellar objects or molecular outflows associated with them. They showed two different velocity components of ~0 and ~16 km/s, which are blue- and red-shifted relative to the adopted systemic velocity of ~7 km/s for NGC 1333. They also showed time variabilities in both intensity and velocity from multi-epoch observations and an anti-correlation between the intensities of the blue- and the red-shifted velocity components. We suggest that the unidentified powering source of these masers might be in the earliest evolutionary stage of star formation before the onset of molecular outflows. Finding this kind of water masers is only possible by an unbiased blind survey. In the 44 GHz methanol maser survey with sensitivity of sigma~0.5 Jy, we confirmed masers toward the IRAS4A2 and the eastern shock region of the IRAS2A. Both sources are also detected in 95 and 132 GHz methanol maser lines. In addition, we had new detections of methanol masers at 95 and 132 GHz toward IRAS4B. In terms of the isotropic luminosity, we detected the methanol maser sources brighter than ~5x1025 erg/s from our unbiased survey.
Towards the pre-stellar core L1544, the methanol (CH$_3$OH) emission forms an asymmetric ring around the core centre, where CH$_3$OH is mostly in solid form, with a clear peak 4000~au to the north-east of the dust continuum peak. As part of the NOEMA Large Project SOLIS (Seeds of Life in Space), the CH$_3$OH peak has been spatially resolved to study its kinematics and physical structure and to investigate the cause behind the local enhancement. We find that methanol emission is distributed in a ridge parallel to the main axis of the dense core. The centroid velocity increases by about 0.2~km~s$^{-1}$ and the velocity dispersion increases from subsonic to transonic towards the central zone of the core, where the velocity field also shows complex structure. This could be indication of gentle accretion of material onto the core or interaction of two filaments, producing a slow shock. We measure the rotational temperature and show that methanol is in local thermodynamic equilibrium (LTE) only close to the dust peak, where it is significantly depleted. The CH$_3$OH column density, $N_{tot}({rm CH_3OH})$, profile has been derived with non-LTE radiative transfer modelling and compared with chemical models of a static core. The measured $N_{tot}({rm CH_3OH})$ profile is consistent with model predictions, but the total column densities are one order of magnitude lower than those predicted by models, suggesting that the efficiency of reactive desorption or atomic hydrogen tunnelling adopted in the model may be overestimated; or that an evolutionary model is needed to better reproduce methanol abundance.
We investigate the kinematics of high mass protostellar objects within the high mass star forming region IRAS 19410+2336. We performed high angular resolution observations of 6.7-GHz methanol and 22 GHz water masers using the MERLIN (Multi-Element Radio Linked Interferometer Network) and e-MERLIN interferometers. The 6.7-GHz methanol maser emission line was detected within the $sim$ 16--27 km s$^{-1}$ velocity range with a peak flux density $sim$50 Jy. The maser spots are spread over $sim$1.3 arcsec on the sky, corresponding to $sim$2800 au at a distance of 2.16 kpc. These are the first astrometric measurements at 6.7 GHz in IRAS 19410+2336. The 22-GHz water maser line was imaged in 2005 and 2019 (the latter with good astrometry). Its velocities range from 13 to $sim$29 km s$^{-1}$. The peak flux density was found to be 18.7 Jy and 13.487 Jy in 2005, and 2019, respectively. The distribution of the water maser components is up to 165 mas, $sim$350 au at 2.16 kpc. We find that the Eastern methanol masers most probably trace outflows from the region of millimetre source mm1. The water masers to the West lie in a disc (flared or interacting with outflow/infall) around another more evolved millimetre source (13-s). The maser distribution suggests that the disc lies at an angle of 60$^{circ}$ or more to the plane of the sky and the observed line of sight velocities then suggest an enclosed mass between 44 M$_{odot}$ and as little as 11 M$_{odot}$ if the disc is edge-on. The Western methanol masers may be infalling.
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