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In interstellar clouds the deposition of water ice onto grains only occurs at visual extinctions above some threshold value A_th. At extinctions greater than A_th there is a (near-linear) correlation between the inferred column density of the water ice and A_V. For individual cloud complexes such as Taurus, Serpens and Rho-Ophiuchi, A_th and the gradients of the correlation are very similar along all lines of sight. We have investigated the origin of this phenomenon, with careful consideration of the various possible mechanisms that may be involved and have applied a full chemical model to analyse the behaviours and sensitivities in quiescent molecular clouds. Our key results are: (i) the ubiquity of the phenomenon points to a common cause, so that the lines of sight probe regions with similar, advanced, chemical and dynamical evolution, (ii) for Taurus and Serpens; A_th and the slope of the correlation can be explained as resulting from the balance of freeze-out of oxygen atoms and photodesorption of H2O molecules. No other mechanism can satisfactorily explain the phenomenon, (iii) A_th depends on the local density, suggesting that there is a correlation between local volume density and column density, (iv) the different values of A_th for Taurus and Serpens are probably due to variations in the local mean radiation field strength, (v) most ice is accreted onto grains that are initially very small (<0.01 microns), and (vi) the very high value of A_th observed in Rho-Ophiuchi cannot be explained in the same way, unless there is complex microstructure and/or a modification to the extinction characteristics.
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Feedback from supernovae is often invoked as an important process in limiting star formation, removing gas from galaxies and hence as a determining process in galaxy formation. Here we report on numerical simulations investigating the interaction between supernova explosions and the natal molecular cloud. We also consider the cases with and without previous feedback from the high-mass star in the form of ionising radiation and stellar winds. The supernova is able to find weak points in the cloud and create channels through which it can escape, leaving much of the well shielded cloud largely unaffected. This effect is increased when the channels are pre-existing due to the effects of previous stellar feedback. The expanding supernova deposits its energy in the gas that is in these exposed channels, and hence sweeps up less mass when feedback has already occurred, resulting in faster outflows with less radiative losses. The full impact of the supernova explosion is then able to impact the larger scale of the galaxy in which it abides. We conclude that supernova explosions only have moderate effects on their dense natal environments but that with pre-existing feedback, the energetic effects of the supernova are able to escape and affect the wider scale medium of the galaxy.
We investigate the shape of the extinction law in two 1-degree square fields of the Perseus Molecular Cloud complex. We combine deep red-optical (r, i, and z-band) observations obtained using Megacam on the MMT with UKIDSS near-infrared (J, H, and K-band) data to measure the colours of background stars. We develop a new hierarchical Bayesian statistical model, including measurement error, intrinsic colour variation, spectral type, and dust reddening, to simultaneously infer parameters for individual stars and characteristics of the population. We implement an efficient MCMC algorithm utilising generalised Gibbs sampling to compute coherent probabilistic inferences. We find a strong correlation between the extinction (Av) and the slope of the extinction law (parameterized by Rv). Because the majority of the extinction toward our stars comes from the Perseus molecular cloud, we interpret this correlation as evidence of grain growth at moderate optical depths. The extinction law changes from the diffuse value of Rv = 3 to the dense cloud value of Rv = 5 as the column density rises from Av = 2 mags to Av = 10 mags. This relationship is similar for the two regions in our study, despite their different physical conditions, suggesting that dust grain growth is a fairly universal process.
The depth-dependent abundance of both gas-phase and solid-state water within dense, quiescent, molecular clouds is important to both the cloud chemistry and gas cooling. Where water is in the gas phase, its free to participate in the network of ion-neutral reactions that lead to a host of oxygen-bearing molecules, and its many ortho and para energy levels make it an effective coolant for gas temperatures greater than 20K. Where water is abundant as ice on grain surfaces, and unavailable to cool the gas, significant amounts of oxygen are removed from the gas phase, suppressing the gas-phase chemical reactions that lead to a number of oxygen-bearing species, including O2. Models of FUV-illuminated clouds predict that the gas-phase water abundance peaks in the range Av ~3 and 8mag of the cloud surface, depending on the gas density and FUV field strength. Deeper within such clouds, water is predicted to exist mainly as ice on grain surfaces. More broadly, these models are used to analyze a variety of other regions, including outflow cavities associated with young stellar objects and the surface layers of protoplanetary disks. In this paper, we report the results of observational tests of FUV-illuminated cloud models toward the Orion Molecular Ridge and Cepheus B using data obtained from the Herschel Space Observatory and the Five College Radio Astronomy Observatory. Toward Orion, 2220 spatial positions were observed along the face-on Orion Ridge in the H2O 110-101 557GHz and NH3 J,K=1,0-0,0 572GHz lines. Toward Cepheus B, two strip scans were made in the same lines across the edge-on ionization front. These new observations demonstrate that gas-phase water exists primarily within a few magnitudes of dense cloud surfaces, strengthening the conclusions of an earlier study based on a much smaller data set, and indirectly supports the prediction that water ice is quite abundant in dense clouds.
C-fractionation has been studied from a theoretical point of view with different models of time-dependent chemistry, including both isotope-selective photodissociation and low-temperature isotopic exchange reactions. Recent chemical models predict that the latter may lead to a depletion of $^{13}$C in nitrile-bearing species, with $^{12}$C/$^{13}$C ratios two times higher than the elemental abundance ratio of 68 in the local ISM. Since the carbon isotopic ratio is commonly used to evaluate the $^{14}$N/$^{15}$N ratios with the double-isotope method, it is important to study C-fractionation in detail to avoid incorrect assumptions. In this work we implemented a gas-grain chemical model with new isotopic exchange reactions and investigated their introduction in the context of dense and cold molecular gas. In particular, we investigated the $^{12}$C/$^{13}$C ratios of HNC, HCN, and CN using a grid of models, with temperatures and densities ranging from 10 to 50 K and 2$times$10$^{3}$ to 2$times$10$^{7}$ cm$^{-3}$, respectively. We suggest a possible $^{13}$C exchange through the $^{13}$C + C$_{3}$ $rightarrow$ $^{12}$C +$^{13}$CC$_{2}$ reaction, which does not result in dilution, but rather in $^{13}$C enhancement, for molecules formed starting from atomic carbon. This effect is efficient in a range of time between the formation of CO and its freeze-out on grains. Furthermore, we show that the $^{12}$C/$^{13}$C ratios of nitriles are predicted to be a factor 0.8-1.9 different from the local value of 68 for massive star-forming regions. This result also affects the $^{14}$N/$^{15}$N ratio: a value of 330 obtained with the double-isotope method is predicted to be 260-1150, depending on the physical conditions. Finally, we studied the $^{12}$C/$^{13}$C ratios by varying the cosmic-ray ionization rate: the ratios increase with it because of secondary photons and cosmic-ray reactions.
We have studied the filaments extracted from the column density maps of the nearby Lupus 1, 3, and 4 molecular clouds, derived from photometric maps observed with the Herschel satellite. Filaments in the Lupus clouds have quite low column densities, with a median value of $sim$1.5$times$10$^{21}$ cm$^{-2}$ and most have masses per unit length lower than the maximum critical value for radial gravitational collapse. Indeed, no evidence of filament contraction has been seen in the gas kinematics. We find that some filaments, that on average are thermally subcritical, contain dense cores that may eventually form stars. This is an indication that in the low column density regime, the critical condition for the formation of stars may be reached only locally and this condition is not a global property of the filament. Finally, in Lupus we find multiple observational evidences of the key role that the magnetic field plays in forming filaments, and determining their confinement and dynamical evolution.
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