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Register a new userQuantum Equilibration under Constraints and Transport Balance
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Authors
Gernot Schaller
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For open quantum systems coupled to a thermal bath at inverse temperature $beta$, it is well known that under the Born-, Markov-, and secular approximations the system density matrix will approach the thermal Gibbs state with the bath inverse temperature $beta$. We generalize this to systems where there exists a conserved quantity (e.g., the total particle number), where for a bath characterized by inverse temperature $beta$ and chemical potential $mu$ we find equilibration of both temperature and chemical potential. For couplings to multiple baths held at different temperatures and different chemical potentials, we identify a class of systems that equilibrates according to a single hypothetical average but in general non-thermal bath, which may be exploited to generate desired non-thermal states. Under special circumstances the stationary state may be again be described by a unique Boltzmann factor. These results are illustrated by several examples.
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We show that the physical mechanism for the equilibration of closed quantum systems is dephasing, and identify the energy scales that determine the equilibration timescale of a given observable. For realistic physical systems (e.g those with local Hamiltonians), our arguments imply timescales that do not increase with the system size, in contrast to previously known upper bounds. In particular we show that, for such Hamiltonians, the matrix representation of local observables in the energy basis is banded, and that this property is crucial in order to derive equilibration times that are non-negligible in macroscopic systems. Finally, we give an intuitive interpretation to recent theorems on equilibration time-scale.
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One of the general mechanisms that give rise to the slow cooperative relaxation characteristic of classical glasses is the presence of kinetic constraints in the dynamics. Here we show that dynamical constraints can similarly lead to slow thermalization and metastability in translationally invariant quantum many-body systems. We illustrate this general idea by considering two simple models: (i) a one-dimensional quantum analogue to classical constrained lattice gases where excitation hopping is constrained by the state of neighboring sites, mimicking excluded-volume interactions of dense fluids; and (ii) fully packed quantum dimers on the square lattice. Both models have a Rokhsar--Kivelson (RK) point at which kinetic and potential energy constants are equal. To one side of the RK point, where kinetic energy dominates, thermalization is fast. To the other, where potential energy dominates, thermalization is slow, memory of initial conditions persists for long times, and separation of timescales leads to pronounced metastability before eventual thermalization. Furthermore, in analogy with what occurs in the relaxation of classical glasses, the slow-thermalization regime displays dynamical heterogeneity as manifested by spatially segregated growth of entanglement.
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