Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userQuantum equilibration of a model system Porphine
90
0
0.0
(
0
)
Ask ChatGPT about the research
No Arabic abstract
There is a renewed interest in the derivation of statistical mechanics from the dynamics of closed quantum systems. A central part of this program is to understand how far-from-equilibrium closed quantum system can behave as if relaxing to a stable equilibrium. Equilibration dynamics has been traditionally studied with a focus on the so-called quenches of large-scale many-body systems. Alternatively, we consider here the equilibration of a molecular model system describing the double proton transfer reaction in porphine. Using numerical simulations, we show that equilibration in this context indeed takes place and does so very rapidly ($sim !! 200$fs) for initial states induced by pump-dump laser pulse control with energies well above the synchronous tunneling barrier.
rate research
Read More
We address the question on how weak perturbations, that are quite ineffective in small many-body systems, can lead to decoherence and hence to irreversibility when they proliferate as the system size increases. This question is at the heart of solid state NMR. There, an initially local polarization spreads all over due to spin-spin interactions that conserve the total spin projection, leading to an equilibration of the polarization. In principle, this quantum dynamics can be reversed by changing the sign of the Hamiltonian. However, the reversal is usually perturbed by non reversible interactions that act as a decoherence source. The fraction of the local excitation recovered defines the Loschmidt echo (LE), here evaluated in a series of closed $N$ spin systems with all-to-all interactions. The most remarkable regime of the LE decay occurs when the perturbation induces proliferated effective interactions. We show that if this perturbation exceeds some lower bound, the decay is ruled by an effective Fermi golden rule (FGR). Such a lower bound shrinks as $ N $ increases, becoming the leading mechanism for LE decay in the thermodynamic limit. Once the polarization stayed equilibrated longer than the FGR time, it remains equilibrated in spite of the reversal procedure.
For open quantum systems coupled to a thermal bath at inverse temperature $beta$, it is well known that under the Born-, Markov-, and secular approximations the system density matrix will approach the thermal Gibbs state with the bath inverse temperature $beta$. We generalize this to systems where there exists a conserved quantity (e.g., the total particle number), where for a bath characterized by inverse temperature $beta$ and chemical potential $mu$ we find equilibration of both temperature and chemical potential. For couplings to multiple baths held at different temperatures and different chemical potentials, we identify a class of systems that equilibrates according to a single hypothetical average but in general non-thermal bath, which may be exploited to generate desired non-thermal states. Under special circumstances the stationary state may be again be described by a unique Boltzmann factor. These results are illustrated by several examples.
Ground states of interacting QFTs are non-gaussian states, i.e. their connected n-point correlation functions do not vanish for n>2, in contrast to the free QFT case. We show that when the ground state of an interacting QFT evolves under a free massive QFT for a long time (a scenario that can be realised by a Quantum Quench), the connected correlation functions decay and all local physical observables equilibrate to values that are given by a gaussian density matrix that keeps memory only of the two-point initial correlation function. The argument hinges upon the fundamental physical principle of cluster decomposition, which is valid for the ground state of a general QFT. An analogous result was already known to be valid in the case of d=1 spatial dimensions, where it is a special case of the so-called Generalised Gibbs Ensemble (GGE) hypothesis, and we now generalise it to higher dimensions. Moreover in the case of massless free evolution, despite the fact that the evolution may not lead to equilibration but unbounded increase of correlations with time instead, the GGE gives correctly the leading order asymptotic behaviour of correlation functions in the thermodynamic and large time limit. The demonstration is performed in the context of bosonic relativistic QFT, but the arguments apply more generally.
A nanoring-rotaxane supramolecular assembly, with a Cy7 cyanine dye (hexamethylindotricarbocyanine) threaded along the axis of the nanoring, has been synthesized as a model for the energy transfer between the light harvesting complex LH1 and the reaction center in purple bacteria photosynthesis. The complex displays efficient energy transfer from the central cyanine dye to the surrounding zinc porphyrin nanoring. We present a theoretical model that reproduces the absorption spectrum of the nanoring and quantifies the excitonic coupling between the nanoring and the central dye, explaining the efficient energy transfer and elucidating the similarity with structurally related natural light harvesting systems.
In this work, we present a result on the non-equilibrium dynamics causing equilibration and Gaussification of quadratic non-interacting fermionic Hamiltonians. Specifically, based on two basic assumptions - clustering of correlations in the initial state and the Hamiltonian exhibiting delocalizing transport - we prove that non-Gaussian initial states become locally indistinguishable from fermionic Gaussian states after a short and well controlled time. This relaxation dynamics is governed by a power-law independent of the system size. Our argument is general enough to allow for pure and mixed initial states, including thermal and ground states of interacting Hamiltonians on and large classes of lattices as well as certain spin systems. The argument gives rise to rigorously proven instances of a convergence to a generalized Gibbs ensemble. Our results allow to develop an intuition of equilibration that is expected to be more generally valid and relates to current experiments of cold atoms in optical lattices.
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
