نفذت الدراسة الحركية على التفاعل بين 1,10- ديكان ديول و الحمض الديميري الدسم C36 في الحالة
المنصهرة، أُنجز التفاعل عند الدرجات .ºC 185, 170, 160, 150, 140 و جرى تعيين قرينة الحموضة
للمنتج.
Kinetic studies were carried out on the reaction between 1,10–
Decanedioland dimeric fatty acid C36 in melt phase. The reaction was
performed at 140, 150, 160, 170, and 185ºC and followed by determining the
acid value of the product.
References used
U. D. N. Bajpai, Nivedita, 1996. Plasticizing polyesters of Dimer acid and 1.4- butanediol, Chemical Engineering journal,chap22,p583-597
U. D. N. Bajpai, Kavita Singh, Nivedita, 2003. Plasticizing polyesters of dimer acid and butane diol, Journal of Applied Polymer Science, V 46, N 8, P 1485 – 1488
Anjali Bajpai, Joshy Simon, 1999. Evaluation of kinetic parameters of dimer acid based metal-containing polyesters using thermo gravimetric analysis, Thermochimica Acta, V334, N 1, P 73-87
Kinetic studies were carried out on the reaction between 2-Methyl 1,5
diaminopentane and dimeric fatty acids in melt phase. The reaction was
performed at 113, 130, 140, 155, and 164 ºC and followed by determining the
acid value of the product .The
Kinetic studies were carried out on the reaction between dimeric fatty acid
C36 with 1.3 Diamino propane and 1.4 Diamino butane and 1.6 Diamino hexane
and 1.8 Diamino octane in molten phase. The reaction was performed at 145ºC.
The polyamidation r
Fattypolyamide was prepared by reaction of (1,5-Diamino pentane) with
dimeric fatty acid C36 in molten state. The reaction was performed at 110 C˚
without catalyst, then with (Phosphoric acid, Sulphoric acid and Manganese
dioxides). The Kinetic st
Kinetic studies were carried out on the reaction between ′4,4-Methylenebis
(2-methylcyclohexylamine) and dimeric fatty acid C36 in molten state by using
a catalyst of sulpheric acid compared with the same kinetic of reaction without
catalyst.
The
Study the kinetics degradation of poly (dimeric acid C36 with 1.9 – diamino
nonane) was carried out by thermal analysis (TGA), and thermodynamic and
equilibrium constants have been defined, moreover, study the kinetics of
reaction between 1.9 – di