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Register a new userPulsed discharge plasma for graphite exfoliation in liquid nitrogen
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Highly Oriented Pyrolytic Graphite was exfoliated via pulsed discharge plasma in liquid nitrogen. The potential mechanisms involved were investigated by observing the treated surface of the graphitic material and the obtained particles. Non-exfoliating defects from the plasma treatment were observed and experimental parameter were modified to counteract those. One experiment was performed without exposing the HOPG directly to the discharges so as to better understand the plasma role. The exfoliated particles were observed via TEM and SEM to evaluate the defects, the size, the purity and the crystallinity but no quantitative characterization of their thickness was possible so the actual number of layer of each particle is unknown. Nonetheless, few layers graphene (FLG) was successfully exfoliated through this process. The proposed mechanisms were extrapolated from the observation of the damaged HOPG surface and the obtained particles but the correlation found does not prove causation.
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Graphene flakes were produced by nanosecond plasma discharge at atmospheric pressure between an electrode and the surface of distilled water, in which were placed graphite flakes. The discharge ionizes the gas and forms free radicals on the surface of the water, functionalizing the graphite flakes in solution. The plasma also gives enough energy to break the Van der Waals bonds between the graphene layers but not enough to break the covalent C-C bonds within the layers. Transmission electron microscopy confirmed the hexagonal structure of graphene sheets, and showed that they were monocrystalline. No contamination was found in the obtained nanomaterial. An unknown phenomenon has been found in the activated distilled water, making its electrical conductivity decrease with an increasing temperature. An acidification of the water is observed. The gas in which the discharge takes place plays a major role on the process, no exfoliation is observed if plasmogen argon gas is used.
In order to break the limitation of plasma nitriding technology,which can be applied to a few nonmetallic gaseous elements, the Double Glow Discharge Phenomenon was found and then invented the Double Glow Plasma Surface Metallurgy Technology. This double glow plasma surface metallurgy technology can use any element in the periodic table of chemical elements for surface alloying of metal materials. Countless surface alloys with special physical and chemical properties have been produced on the surfaces of conductive materials.By using double glow discharge phenomenon,a series of new plasma technologies,such as the double glow plasma graphene technology, double glow plasma brazing technology,double glow plasma sintering technology, double glow plasma nanotechnology,double glow plasma cleaning technology, double glow plasma carburizing without hydrogen and so on, have been invented.A very simple phenomenon of double glow discharge can generate about 10 plasma innovation technologies, which fully shows that there is still a lot of innovation space on the basis of classical physics.This paper briefly introduces the basic principles,functions and characteristics of each technology. The application prospects and development directions of plasma in metal materials and machinery manufacturing industry will also be discussed.
Synthesis of graphene with reduced use of chemical reagents is essential for manufacturing scale-up and to control its structure and properties. In this paper, we report on a novel chemical-free mechanism of graphene exfoliation from graphite using laser impulse. Our experimental setup consists of a graphite slab irradiated with an Nd:YAG laser of wavelength 532 nm and 10 ns pulse width. The results show the formation of graphene layers with conformational morphology from electron microscopy and Raman spectra. Based on the experimental results, we develop a simulation set up within the framework of the molecular dynamics that supplies the laser-induced electromagnetic energies to atoms in the graphite slab. We investigate the influence of different laser fluence on the exfoliation process of graphene. The variations in inter-layer interaction energy and inter-layer distance are the confirmative measures for the possible graphene layer formation. The simulation results confirm the exfoliation of a single layer graphene sheet for the laser power ranging from 100x10^(-14) to 2000x10^(-14) J/nm2. With an increase of laser fluence from 2000x10^(-14) to 4000x10^(-14) J/nm2, there is an increase in the graphene yield via the layer-after-layer exfoliation. The bridging bond dynamics between the successive graphene layers govern the possibility of second-layer exfoliation. The experimental and simulation observations are useful and promising for producing chemical-free graphene on a large scale for industrial and commercial applications.
This article proposes a scheme for nitrogen-vacancy (NV) center magnetometry that combines the advantages of lock-in detection and pulse-type scheme. The optimal conditions, optimal sensitivity, and noise-suppression capability of the proposed method are compared with those of the conventional methods from both theoretical and simulation points of view. Through experimental measurements, a four-time improvement in sensitivity and 60-times improvement in minimum resolvable magnetic field (MRMF) was obtained. By using a confocal experiment setup, proposed scheme achieves a sensitivity of 3 nT/Hz1/2 and a MRMF of 100 pT.
Plasma Surface Metallurgy/Alloying is a kind of surface metallurgy/alloying to employ low temperature plasma produced by glow discharge to diffuse alloying elements into the surface of substrate material to form an alloy layer. The first plasma surface metallurgy technology is plasma nitriding invented by German scientist Dr. Bernard Berghuas in 1930. He was the first person to apply glow discharge to realize the surface alloying. In order to break the limitation of plasma nitriding technology, which can only be applied to a few non-metallic gaseous elements such as nitrogen, carbon, sulfur, the Double Glow Discharge Phenomenonwas found in 1978. Based on this phenomenon the Double Glow Plasma Surface Metallurgy Technology, also known as the Xu-Tec Process was invented in 1980. It can utilize any chemical elements in the periodic table including solid metallic, gas non-metallic elements and their combination to realize plasma surface alloying, hence greatly expanded the field of surface alloying. Countless surface alloys with high hardness, wear resistance and corrosion resistance, such as high speed steels, nickel base alloys and burn resistant alloys have been produced on the surfaces of a variety of materials. This technology may greatly improve the surface properties of metal materials, comprehensively improve the quality of mechanical products, save a lot of precious alloy elements for human beings. Based on the plasma nitriding technology, the Xu-Tec Process has opened up a new material engineering field of Plasma Surface Metallurgy. This Review Article briefly presents the history of glow discharge and surface alloying, double glow discharge phenomenon, basic principle and current status of Double Glow Plasma Surface Metallurgy/Alloying. Industrial applications, advantages and future potential of the Xu-Tec process are also presented.
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