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We describe a method, based on hard contact topology, of showing the existence of semi-infinite trajectories of contact Hamiltonian flows which start on one Legendrian submanifold and asymptotically converge to another Legendrian submanifold. We discuss a mathematical model of non-equilibrium thermodynamics where such trajectories play a role of relaxation processes, and illustrate our results in the case of the Glauber dynamics for the mean field Ising model.
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In the setting of the principle of local equilibrium which asserts that the temperature is a function of the energy levels of the system, we exhibit plenty of steady states describing the condensation of free Bosons which are not in thermal equilibrium. The surprising facts are that the condensation can occur both in dimension less than 3 in configuration space, and even in excited energy levels. The investigation relative to non equilibrium suggests a new approach to the condensation, which allows an unified analysis involving also the condensation of $q$-particles, $-1leq qleq 1$, where $q=pm1$ corresponds to the Bose/Fermi alternative. For such $q$-particles, the condensation can occur only if $0<qleq1$, the case 1 corresponding to the standard Bose-Einstein condensation. In this more general approach, completely new and unexpected states exhibiting condensation phenomena naturally occur also in the usual situation of equilibrium thermodynamics. The new approach proposed in the present paper for the situation of $2^text{nd}$ quantisation of free particles, is naturally based on the theory of the Distributions, which might hopefully be extended to more general cases
Metriplectic systems are state space formulations that have become well-known under the acronym GENERIC. In this work we present a GENERIC based state space formulation in an operator setting that encodes a weak-formulation of the field equations describing the dynamics of a homogeneous mixture of compressible heat-conducting Newtonian fluids consisting of reactive constituents. We discuss the mathematical model of the fluid mixture formulated in the framework of continuum thermodynamics. The fluid mixture is considered an open thermodynamic system that moves free of external body forces. As closure relations we use the linear constitutive equations of the phenomenological theory known as Thermodynamics of Irreversible Processes (TIP). The phenomenological coefficients of these linear constitutive equations satisfy the Onsager-Casimir reciprocal relations. We present the state space representation of the fluid mixture, formulated in the extended GENERIC framework for open systems, specified by a symmetric, mixture related dissipation bracket and a mixture related Poisson-bracket for which we prove the Jacobi-identity.
We propose a variational formulation for the nonequilibrium thermodynamics of discrete open systems, i.e., discrete systems which can exchange mass and heat with the exterior. Our approach is based on a general variational formulation for systems with time-dependent nonlinear nonholonomic constraints and time-dependent Lagrangian. For discrete open systems, the~time-dependent nonlinear constraint is associated with the rate of internal entropy production of the system. We show that this constraint on the solution curve systematically yields a constraint on the variations to be used in the action functional. The proposed variational formulation is intrinsic and provides the same structure for a wide class of discrete open systems. We illustrate our theory by presenting examples of open systems experiencing mechanical interactions, as well as internal diffusion, internal heat transfer, and their cross-effects. Our approach yields a systematic way to derive the complete evolution equations for the open systems, including the expression of the internal entropy production of the system, independently on its complexity. It might be especially useful for the study of the nonequilibrium thermodynamics of biophysical systems.
We formulate and prove a very general relative version of the Dobrushin-Lanford-Ruelle theorem which gives conditions on constraints of configuration spaces over a finite alphabet such that for every absolutely summable relative interaction, every translation-invariant relative Gibbs measure is a relative equilibrium measure and vice versa. Neither implication is true without some assumption on the space of configurations. We note that the usual finite type condition can be relaxed to a much more general class of constraints. By relative we mean that both the interaction and the set of allowed configurations are determined by a random environment. The result includes many special cases that are well known. We give several applications including (1) Gibbsian properties of measures that maximize pressure among all those that project to a given measure via a topological factor map from one symbolic system to another; (2) Gibbsian properties of equilibrium measures for group shifts defined on arbitrary countable amenable groups; (3) A Gibbsian characterization of equilibrium measures in terms of equilibrium condition on lattice slices rather than on finite sets; (4) A relative extension of a theorem of Meyerovitch, who proved a version of the Lanford--Ruelle theorem which shows that every equilibrium measure on an arbitrary subshift satisfies a Gibbsian property on interchangeable patterns.
Standard derivations of the functional integral in non-equilibrium quantum field theory are based on the discrete time representation. In this work we derive the non-equilibrium functional integral for non-interacting bosons and fermions using a continuum time approach by accounting for the statistical distribution through the boundary conditions and using them to evaluate the Greens function.
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