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Register a new userQuantum sensing and control of spin state dynamics in the radical pair mechanism
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Radical pairs and the dynamics they undergo are prevalent in many chemical and biological systems. Specifically, it has been proposed that the radical pair mechanism results from a relatively strong hyperfine interaction with its intrinsic nuclear spin environment. While the existence of this mechanism is undisputed, the nanoscale details remain to be experimentally shown. We analyze here the role of a quantum sensor in detecting the spin dynamics (non-Markovian) of individual radical pairs in the presence of a weak magnetic field. We show how quantum control methods can be used to set apart the dynamics of radical pair mechanism at various stages of the evolution. We envisage these findings having far-reaching implications to the understanding of the physical mechanism in magnetoreception and other bio-chemical processes with a microscopic detail.
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The measured multi-dimensional spectral response of different light harvesting complexes exhibits oscillatory features which suggest an underlying coherent energy transfer. However, making this inference rigorous is challenging due to the difficulty of isolating excited state coherences in highly congested spectra. In this work, we provide a coherent control scheme that suppresses ground state coherences, thus making rephasing spectra dominated by excited state coherences. We provide a benchmark for the scheme using a model dimeric system and numerically exact methods to analyze the spectral response. We argue that combining temporal and spectral control methods can facilitate a second generation of experiments that are tailored to extract desired information and thus significantly advance our understanding of complex open many-body structure and dynamics.
The paper reports an exact solution for the problem of spin evolution of radical ion pair in static magnetic and resonant microwave field taking into account Zeeman and hyperfine interactions and spin relaxation. The values of parameters that provide one of the four possible types of solution are analysed. It is demonstrated that in the absence of spin relaxation, besides the zero field invariant an invariant at large amplitudes of the resonant microwave field can be found. The two invariants open the possibility for simple calculation of microwave pulses to control quantum state of the radical pair. The effect of relaxation on the invariants is analysed and it is shown that changes in the high field invariant are induced by phase relaxation.
There is a deep connection between the ground states of transverse-field spin systems and the late-time distributions of evolving viral populations -- within simple models, both are obtained from the principal eigenvector of the same matrix. However, that vector is the wavefunction amplitude in the quantum spin model, whereas it is the probability itself in the population model. We show that this seemingly minor difference has significant consequences: phase transitions which are discontinuous in the spin system become continuous when viewed through the population perspective, and transitions which are continuous become governed by new critical exponents. We introduce a more general class of models which encompasses both cases, and that can be solved exactly in a mean-field limit. Numerical results are also presented for a number of one-dimensional chains with power-law interactions. We see that well-worn spin models of quantum statistical mechanics can contain unexpected new physics and insights when treated as population-dynamical models and beyond, motivating further studies.
We describe quantum limits to field sensing that relate noise, geometry and measurement duration to fundamental constants, with no reference to particle number. We cast the Tesche and Clarke (TC) bound on dc-SQUID sensitivity as such a limit, and find analogous limits for volumetric spin-precession magnetometers. We describe how randomly-arrayed spins, coupled to an external magnetic field of interest and to each other by the magnetic dipole-dipole interaction, execute a spin dynamics that depolarizes the spin ensemble even in the absence of coupling to an external reservoir. We show the resulting spin dynamics are scale invariant, with a depolarization rate proportional to spin number density and thus a number-independent quantum limit on the energy resolution per bandwidth $E_R$. Numerically, we find $E_R ge alpha hbar$, $alpha sim 1$, in agreement with the TC limit, for paradigmatic spin-based measurements of static and oscillating magnetic fields.
The mechanism used by migratory birds to orientate themselves using the geomagnetic field is still a mystery in many species. The radical pair mechanism, in which very weak magnetic fields can influence certain types of spin-dependent chemical reactions, leading to biologically observable signals, has recently imposed itself as one of the most promising candidates for certain species. This is thanks both to its extreme sensitivity and its capacity to reproduce results from behavioral studies. Still, in order to gain a directional sensitivity, an anisotropic mechanism is needed. Recent proposals have explored the possibility that such an anisotropy is due to the electron-nucleus hyperfine interaction. In this work we explore a different possibility, in which the anisotropy is due to spin-orbit coupling between the electron spin and its angular momentum. We will show how a spin-orbit-coupling-based magnetic compass can have performances comparable with the usually-studied nuclear-hyperfine based mechanism. Our results could thus help researchers actively looking for candidate biological molecules which may host magnetoreceptive functions, both to describe magnetoreception in birds as well as to develop artificial chemical compass systems.
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