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Register a new userSpecific Heat of Ising Model with Holes: Mathematical Details Using Dimer Approaches
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In this paper, we use the dimer method to obtain the free energy of Ising models consisting of repeated horizontal strips of width $m$ connected by sequences of vertical strings of length $n$ mutually separated by distance $N$, with $N$ arbitrary, to investigate the effects of connectivity and proximity on the specific heat. The decoration method is used to transform the strings of $n+1$ spins interacting with their nearest neighbors with coupling $J$ into a pair with coupling $bar J$ between the two spins. The free energy per site is given as a single integral and some results for critical temperatures are derived.
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The bond-propagation (BP) algorithm for the specific heat of the two dimensional Ising model is developed and that for the internal energy is completed. Using these algorithms, we study the critical internal energy and specific heat of the model on the square lattice and triangular lattice with free boundaries. Comparing with previous works [X.-T. Wu {it et al} Phys. Rev. E {bf 86}, 041149 (2012) and Phys. Rev. E {bf 87}, 022124 (2013)], we reach much higher accuracy ($10^{-26}$) of the internal energy and specific heat, compared to the accuracy $10^{-11}$ of the internal energy and $10^{-9}$ of the specific heat reached in the previous works. This leads to much more accurate estimations of the edge and corner terms. The exact values of some edge and corner terms are therefore conjectured. The accurate forms of finite-size scaling for the internal energy and specific heat are determined for the rectangle-shaped square lattice with various aspect ratios and various shaped triangular lattice. For the rectangle-shaped square and triangular lattices and the triangle-shaped triangular lattice, there is no logarithmic correction terms of order higher than 1/S, with S the area of the system. For the triangular lattice in rhombus, trapezoid and hexagonal shapes, there exist logarithmic correction terms of order higher than 1/S for the internal energy, and logarithmic correction terms of all orders for the specific heat.
We study a two dimensional Ising model between thermostats at different temperatures. By applying the recently introduced KQ dynamics, we show that the system reaches a steady state with coexisting phases transversal to the heat flow. The relevance of such complex states on thermodynamic or geometrical observables is investigated. In particular, we study energy, magnetization and metric properties of interfaces and clusters which, in principle, are sensitive to local features of configurations. With respect to equilibrium states, the presence of the heat flow amplifies the fluctuations of both thermodynamic and geometrical observables in a domain around the critical energy. The dependence of this phenomenon on various parameters (size, thermal gradient, interaction) is discussed also with reference to other possible diffusive models.
The theoretical model proposed by Einstein to describe the phononic specific heat of solids as a function of temperature consists the very first application of the concept of energy quantization to describe the physical properties of a real system. Its central assumption lies in the consideration of a total energy distribution among N (in the thermodynamic limit $N rightarrow infty$) non-interacting oscillators vibrating at the same frequency ($omega$). Nowadays, it is well-known that most materials behave differently at the nanoscale, having thus some cases physical properties with potential technological applications. Here, a version of the Einsteins model composed of a finite number of particles/oscillators is proposed. The main findings obtained in the frame of the present work are: (i) a qualitative description of the specific heat in the limit of low-temperatures for systems with nano-metric dimensions; (ii) the observation that the corresponding chemical potential function for finite solids becomes null at finite temperatures as observed in the Bose-Einstein condensation and; (iii) emergence of a first-order like phase transition driven by varying $N$.
In order to investigate the effects of connectivity and proximity in the specific heat, a special class of exactly solvable planar layered Ising models has been studied in the thermodynamic limit. The Ising models consist of repeated uniform horizontal strips of width $m$ connected by sequences of vertical strings of length $n$ mutually separated by distance $N$, with $N=1,2$ and $3$. We find that the critical temperature $T_c(N,m,n)$, arising from the collective effects, decreases as $n$ and $N$ increase, and increases as $m$ increases, as it should be. The amplitude $A(N,m,n)$ of the logarithmic divergence at the bulk critical temperature $T_c(N,m,n)$ becomes smaller as $n$ and $m$ increase. A rounded peak, with size of order $ln m$ and signifying the one-dimensional behavior of strips of finite width $m$, appears when $n$ is large enough. The appearance of these rounded peaks does not depend on $m$ as much, but depends rather more on $N$ and $n$, which is rather perplexing. Moreover, for fixed $m$ and $n$, the specific heats are not much different for different $N$. This is a most surprising result. For $N=1$, the spin-spin correlation in the center row of each strip can be written as a Toeplitz determinant with a generating function which is much more complicated than in Onsagers Ising model. The spontaneous magnetization in that row can be calculated numerically and the spin-spin correlation is shown to have two-dimensional Ising behavior.
We show that systems with negative specific heat can violate the zeroth law of thermodynamics. By both numerical simulations and by using exact expressions for free energy and microcanonical entropy it is shown that if two systems with the same intensive parameters but with negative specific heat are thermally coupled, they undergo a process in which the total entropy increases irreversibly. The final equilibrium is such that two phases appear, that is, the subsystems have different magnetizations and internal energies at temperatures which are equal in both systems, but that can be different from the initial temperature.
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