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Register a new userCSO and CARMA Observations of L1157. II. Chemical Complexity in the Shocked Outflow
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L1157, a molecular dark cloud with an embedded Class 0 protostar possessing a bipolar outflow, is an excellent source for studying shock chemistry, including grain-surface chemistry prior to shocks, and post-shock, gas-phase processing. The L1157-B1 and B2 positions experienced shocks at an estimated ~2000 and 4000 years ago, respectively. Prior to these shock events, temperatures were too low for most complex organic molecules to undergo thermal desorption. Thus, the shocks should have liberated these molecules from the ice grain-surfaces en masse, evidenced by prior observations of SiO and multiple grain mantle species commonly associated with shocks. Grain species, such as OCS, CH3OH, and HNCO, all peak at different positions relative to species that are preferably formed in higher velocity shocks or repeatedly-shocked material, such as SiO and HCN. Here, we present high spatial resolution (~3) maps of CH3OH, HNCO, HCN, and HCO+ in the southern portion of the outflow containing B1 and B2, as observed with CARMA. The HNCO maps are the first interferometric observations of this species in L1157. The maps show distinct differences in the chemistry within the various shocked regions in L1157B. This is further supported through constraints of the molecular abundances using the non-LTE code RADEX (Van der Tak et al. 2007). We find the east/west chemical differentiation in C2 may be explained by the contrast of the shocks interaction with either cold, pristine material or warm, previously-shocked gas, as seen in enhanced HCN abundances. In addition, the enhancement of the HNCO abundance toward the the older shock, B2, suggests the importance of high-temperature O-chemistry in shocked regions.
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A deep search for the potential glycine precursor hydroxylamine (NH$_2$OH) using the Caltech Submillimeter Observatory (CSO) at $lambda = 1.3$ mm and the Combined Array for Research in Millimeter-wave Astronomy (CARMA) at $lambda = 3$ mm is presented toward the molecular outflow L1157, targeting the B1 and B2 shocked regions. We report non-detections of NH$_2$OH in both sources. We a perform non-LTE analysis of CH$_3$OH observed in our CSO spectra to derive kinetic temperatures and densities in the shocked regions. Using these parameters, we derive upper limit column densities of NH$_2$OH of $leq1.4 times 10^{13}$~cm$^{-2}$ and $leq1.5 times 10^{13}$~cm$^{-2}$ toward the B1 and B2 shocks, respectively, and upper limit relative abundances of $N_{NH_2OH}/N_{H_2} leq1.4 times 10^{-8}$ and $leq1.5 times 10^{-8}$, respectively.
In the framework of the WISH key program, several H2O (E_u>190 K), high-J CO, [OI], and OH transitions are mapped with PACS in two shock positions along the two prototypical low-luminosity outflows L1448 and L1157. Previous HIFI H2O observations (E_u=53-249 K) and complementary Spitzer mid-IR H2 data are also used, with the aim of deriving a complete picture of the excitation conditions. At all selected spots a close spatial association between H2O, mid-IR H2, and high-J CO emission is found, whereas the low-J CO emission traces either entrained ambient gas or a remnant of an older shock. The excitation analysis at L1448-B2 suggests that a two-component model is needed to reproduce the H2O, CO, and mid-IR H2 lines: an extended warm component (T~450 K) is traced by the H2O emission with E_u =53-137 K and by the CO lines up to J=22-21, and a compact hot component (T=1100 K) is traced by the H2O emission with E_u>190 K and by the higher-J CO lines. At L1448-B2 we obtain an H2O abundance (3-4)x10^{-6} for the warm component and (0.3-1.3)x10^{-5} for the hot component; we also detect OH and blue-shifted [OI] emission, spatially coincident with the other molecular lines and with [FeII] emission. This suggests a dissociative shock for these species, related to the embedded atomic jet. On the other hand, a non-dissociative shock at the point of impact of the jet on the cloud is responsible for the H2O and CO emission. The other examined shock positions show an H2O excitation similar to L1448-B2, but a slightly higher H2O abundance (a factor of 4). The two gas components may represent a gas stratification in the post-shock region. The extended and low-abundance warm component traces the post-shocked gas that has already cooled down to a few hundred Kelvin, whereas the compact and possibly higher-abundance hot component is associated with the gas that is currently undergoing a shock episode.
The isotopic ratio of nitrogen presents a wide range of values in the Solar System and in star forming system whose origin is still unclear. Chemical reactions in the gas phase are one of the possible processes that could modify the $^{14}$N/$^{15}$N ratio. We aim at investigating if and how the passage of a shock wave in the interstellar medium, can affect the relative fraction of nitrogen isotopes. The ideal place for such a study is the L1157 outflow, where several shocked clumps are present. We present the first measurement of the $^{14}$N/$^{15}$N ratio in the two shocked clumps, B1 and B0, of the protostellar outflow L1157, derived from the interferomteric maps of the H$^{13}$CN(1-0) and the HC$^{15}$N(1-0) lines. In B1, we find that the H$^{13}$CN(1-0) and HC$^{15}$N(1-0) emission traces the front of the clump, with averaged column density of $N$(H$^{13}$CN) $sim$ 7$times$10$^{12}$ cm$^{-2}$ and $N$(HC$^{15}$N) $sim$ 2$times$10$^{12}$ cm$^{-2}$. In this region the ratio H$^{13}$CN(1-0)/HC$^{15}$N(1-0) is quite uniform with an average value of $sim$ 5$pm$1. The same average value is also measured in the smaller clump B0e. Assuming the standard $^{12}$C/$^{13}$C = 68, we obtain $^{14}$N/$^{15}$N = 340$pm$70, similar to those usually found in prestellar cores and protostars. We analysed the prediction of a chemical shock model for several shock conditions and we found that the nitrogen and carbon fractionations do not vary much for the first period after the shock. The observed H$^{13}$CN/HC$^{15}$N can be reproduced by a non-dissociative, C-type shock with parameters in agreement with previous modelling of L1157-B1. Both observations and chemical models indicate that the shock propagation does not affect the nitrogen isotopic ratio that remains similar to that measured in lower temperature gas in prestellar cores and in protostellar envelopes.
We present a multiline CS survey towards the brightest bow-shock B1 in the prototypical chemically active protostellar outflow L1157. We made use of (sub-)mm data obtained in the framework of the Chemical HErschel Surveys of Star forming regions (CHESS) and Astrochemical Surveys at IRAM (ASAI) key science programs. We detected $^{12}$C$^{32}$S, $^{12}$C$^{34}$S, $^{13}$C$^{32}$S, and $^{12}$C$^{33}$S emissions, for a total of 18 transitions, with $E_{rm u}$ up to $sim$ 180 K. The unprecedented sensitivity of the survey allows us to carefully analyse the line profiles, revealing high-velocity emission, up to 20 km s$^{-1}$ with respect to the systemic. The profiles can be well fitted by a combination of two exponential laws that are remarkably similar to what previously found using CO. These components have been related to the cavity walls produced by the $sim$ 2000 yr B1 shock and the older ($sim$ 4000 yr) B2 shock, respectively. The combination of low- and high-excitation CS emission was used to properly sample the different physical components expected in a shocked region. Our CS observations show that this molecule is highlighting the dense, $n_{rm H_2}$ = 1--5 $times$ 10$^{5}$ cm$^{-3}$, cavity walls produced by the episodic outflow in L1157. In addition, the highest excitation (E$_u$ $geq$ 130 K) CS lines provide us with the signature of denser (1--5 $times$ 10$^{6}$ cm$^{-3}$) gas, associated with a molecular reformation zone of a dissociative J-type shock, which is expected to arise where the precessing jet impacting the molecular cavities. The CS fractional abundance increases up to $sim$ 10$^{-7}$ in all the kinematical components. This value is consistent with what previously found for prototypical protostars and it is in agreement with the prediction of the abundances obtained via the chemical code Astrochem.
We present observations of SO and $rm SO_2$ lines toward the shocked regions along the L1157 chemically rich outflow, taken in the context of the Seeds Of Life In Space IRAM-NOrthern Extended Millimeter Array Large Program, and supported by data from Submillimeter Array and IRAM-30 m telescope at 1.1--3.6 mm wavelengths. We simultaneously analyze, for the first time, all of the brightest shocks in the blueshifted lobe, namely, B0, B1, and B2. We found the following. (1) SO and $rm SO_2$ may trace different gas, given that the large(-scale) velocity gradient analysis indicates for $rm SO_2$ a volume density ($rm 10^5text{--}10^6,cm^{-3}$) denser than that of the gas emitting in SO by a factor up to an order of magnitude. (2) Investigating the 0.1 pc scale field of view, we note a tentative gradient along the path of the precessing jet. More specifically, $rm chi({SO/SO_2})$ decreases from the B0-B1 shocks to the older B2. (3) At a linear resolution of 500--1400 au, a tentative spatial displacement between the two emitting molecules is detected, with the SO peak closer (with respect to $rm SO_2$) to the position where the recent jet is impinging on the B1 cavity wall. Our astrochemical modeling shows that the SO and $rm SO_2$ abundances evolve on timescales less than about 1000 years. Furthermore, the modeling requires high abundances ($2times10^{-6}$) of both $rm H_2S/H$ and S/H injected in the gas phase due to the shock occurrence, so pre-frozen OCS only is not enough to reproduce our new observations.
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