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Register a new userCSO and CARMA Observations of L1157. I. A Deep Search for Hydroxylamine (NH$_2$OH)
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A deep search for the potential glycine precursor hydroxylamine (NH$_2$OH) using the Caltech Submillimeter Observatory (CSO) at $lambda = 1.3$ mm and the Combined Array for Research in Millimeter-wave Astronomy (CARMA) at $lambda = 3$ mm is presented toward the molecular outflow L1157, targeting the B1 and B2 shocked regions. We report non-detections of NH$_2$OH in both sources. We a perform non-LTE analysis of CH$_3$OH observed in our CSO spectra to derive kinetic temperatures and densities in the shocked regions. Using these parameters, we derive upper limit column densities of NH$_2$OH of $leq1.4 times 10^{13}$~cm$^{-2}$ and $leq1.5 times 10^{13}$~cm$^{-2}$ toward the B1 and B2 shocks, respectively, and upper limit relative abundances of $N_{NH_2OH}/N_{H_2} leq1.4 times 10^{-8}$ and $leq1.5 times 10^{-8}$, respectively.
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L1157, a molecular dark cloud with an embedded Class 0 protostar possessing a bipolar outflow, is an excellent source for studying shock chemistry, including grain-surface chemistry prior to shocks, and post-shock, gas-phase processing. The L1157-B1 and B2 positions experienced shocks at an estimated ~2000 and 4000 years ago, respectively. Prior to these shock events, temperatures were too low for most complex organic molecules to undergo thermal desorption. Thus, the shocks should have liberated these molecules from the ice grain-surfaces en masse, evidenced by prior observations of SiO and multiple grain mantle species commonly associated with shocks. Grain species, such as OCS, CH3OH, and HNCO, all peak at different positions relative to species that are preferably formed in higher velocity shocks or repeatedly-shocked material, such as SiO and HCN. Here, we present high spatial resolution (~3) maps of CH3OH, HNCO, HCN, and HCO+ in the southern portion of the outflow containing B1 and B2, as observed with CARMA. The HNCO maps are the first interferometric observations of this species in L1157. The maps show distinct differences in the chemistry within the various shocked regions in L1157B. This is further supported through constraints of the molecular abundances using the non-LTE code RADEX (Van der Tak et al. 2007). We find the east/west chemical differentiation in C2 may be explained by the contrast of the shocks interaction with either cold, pristine material or warm, previously-shocked gas, as seen in enhanced HCN abundances. In addition, the enhancement of the HNCO abundance toward the the older shock, B2, suggests the importance of high-temperature O-chemistry in shocked regions.
We present here a systematic search for cyanopolyynes in the shock region L1157-B1 and its associated protostar L1157-mm in the framework of the Large Program Astrochemical Surveys At IRAM (ASAI), dedicated to chemical surveys of solar-type star forming regions with the IRAM 30m telescope. Observations of the millimeter windows between 72 and 272 GHz permitted the detection of HC$_3$N and its $^{13}$C isotopologues, and HC$_5$N (for the first time in a protostellar shock region). In the shock, analysis of the line profiles shows that the emission arises from the outflow cavities associated with L1157-B1 and L1157-B2. Molecular abundances and excitation conditions were obtained from analysis of the Spectral Line Energy Distributions under the assumption of Local Thermodynamical Equilibrium or using a radiative transfer code in the Large Velocity Gradient approximation. Towards L1157mm, the HC$_3$N emission arises from the cold envelope ($T_{rot}=10$ K) and a higher-excitation region ($T_{rot}$= $31$ K) of smaller extent around the protostar. We did not find any evidence of $^{13}$C or D fractionation enrichment towards L1157-B1. We obtain a relative abundance ratio HC$_3$N/HC$_5$N of 3.3 in the shocked gas. We find an increase by a factor of 30 of the HC$_3$N abundance between the envelope of L1157-mm and the shock region itself. Altogether, these results are consistent with a scenario in which the bulk of HC$_3$N was produced by means of gas phase reactions in the passage of the shock. This scenario is supported by the predictions of a parametric shock code coupled with the chemical model UCL_CHEM.
The OH molecule, found abundantly in the Milky Way, has four transitions at the ground state rotational level(J = 3/2) at cm wavelengths. These are E1 transitions between the F+ and F- hyperfine levels of the Lambda doublet of the J=3/2 state. There are also forbidden M1 transitions between the hyperfine levels within each of the doublet states occuring at frequencies 53.171 MHz and 55.128 MHz. These are extremely weak and hence difficult to detect. However there is a possibility that the level populations giving rise to these lines are inverted under special conditions, in which case it may be possible to detect them through their maser emission. We describe the observational diagnostics for determining when the hyperfine levels are inverted, and identify a region near W44 where these conditions are satisfied. A high-velocity-resolution search for these hyperfine OH lines using the low frequency feeds on four antennas of the GMRT and the new GMRT Software Backend(GSB) was performed on this target near W44. We place a 3-sigma upper limit of ~17.3 Jy (at 1 km/s velocity resolution) for the 55 MHz line from this region. This corresponds to an upper limit of 3 X 10^8 for the amplification of the Galactic synchrotron emission providing the background.
Centimeter-wave transitions are important counterparts to the rotational mm-wave transitions usually observed to study gas in star-forming regions. However, given their relative weakness, these transitions have historically been neglected. We present Australia Telescope Compact Array 4cm- and 15mm-band spectral line observations of nine nearby star-forming galaxies in the H75 array configuration. Thirteen different molecular lines are detected across the sample from OH, NH$_3$, H$_2$O, H$_2$CO, and c-C$_3$H$_2$, as well as 18 radio recombination lines (RRLs) in NGC 253. Excited OH $^2Pi_{3/2}$ absorption is detected towards NGC 253 (J=5/2), NGC 4945 (J=9/2), and Circinus (J=9/2); the latter two represent only the third and fourth extragalactic J=9/2 detections. These lines in Circinus suggest rotation temperatures in excess of 2000 K, and thus it is likely that the populations of OH rotational states are not governed by a Boltzmann distribution. Circinuss OH lines are blueshifted from the systemic velocity by ~35 km s$^{-1}$, while NGC 4945s are redshifted by ~100 km s$^{-1}$. NGC 4945s OH absorption likely indicates infall onto the nucleus. The NH$_3$ (1,1) through (6,6) lines in NGC 4945 display a superposition of emission and absorption similar to that seen in other dense gas tracers. Strong (3,3) emission points towards maser activity. The relative NH$_3$ absorption strengths in NGC 4945 show similar anomalies as in previous studies of Arp 220 (weak (1,1) and strong (5,5) absorption). A trend towards higher LTE electron temperatures with increasing RRL frequency is present in NGC 253, likely indicative of stimulated emission within the nuclear region.
OH absorption is currently the only viable way to detect OH molecules in non-masing galaxies at cosmological distances. There have been only 6 such detections at z>0.05 to date and so it is hard to put a statistically robust constraint on OH column densities in distant galaxies. We carried out a pilot OH absorption survey towards 8 associated and 1 intervening HI 21-cm absorbers using the Five-hundred-meter Aperture Spherical radio Telescope (FAST). We were able to constrain the OH abundance relative to HI ([OH]/[HI]) to be lower than 10^-6 ~ 10^-8 for redshifts z within [0.1919, 0.2241]. Although no individual detection was made, stacking three associated absorbers free of RFI provides a sensitive OH column density 3-sigma upper-limit ~ 1.57 x 10^14 (Tx/10K)(1/fc) cm^-2, which corresponds to a [OH]/[HI] < 5.45 x 10^-8. Combining with archival data, we show that associated absorbers have a slightly lower OH abundance than intervening absorbers. Our results are consistent with a trend of decreasing OH abundance with decreasing redshift.
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