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Microscopic theory of a phase transition in a critical region: Bose-Einstein condensation in an interacting gas

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 Added by Vitaly Kocharovsky
 Publication date 2015
  fields Physics
and research's language is English




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We present a microscopic theory of the second order phase transition in an interacting Bose gas that allows one to describe formation of an ordered condensate phase from a disordered phase across an entire critical region continuously. We derive the exact fundamental equations for a condensate wave function and the Green functions, which are valid both inside and outside the critical region. They are reduced to the usual Gross-Pitaevskii and Beliaev-Popov equations in a low-temperature limit outside the critical region. The theory is readily extendable to other phase transitions, in particular, in the physics of condensed matter and quantum fields.



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The problem of finding a microscopic theory of phase transitions across a critical point is a central unsolved problem in theoretical physics. We find a general solution to that problem and present it here for the cases of Bose-Einstein condensation in an interacting gas and ferromagnetism in a lattice of spins, interacting via a Heisenberg or Ising Hamiltonian. For Bose-Einstein condensation, we present the exact, valid for the entire critical region, equations for the Green functions and order parameter, that is a critical-region extension of the Beliaev-Popov and Gross-Pitaevskii equations. For the magnetic phase transition, we find an exact theory in terms of constrained bosons in a lattice and obtain similar equations for the Green functions and order parameter. In particular, we outline an exact solution for the three-dimensional Ising model.
We find universal structure and scaling of BEC statistics and thermodynamics for mesoscopic canonical-ensemble ideal gas in a trap for any parameters, including critical region. We identify universal constraint-cut-off mechanism that makes BEC fluctuations non-Gaussian and is responsible for critical phenomena. Main result is analytical solution to problem of critical phenomena. It is derived by calculating universal distribution of noncondensate occupation (Landau function) and then universal functions for physical quantities. We find asymptotics of that solution and its approximations which describe universal structure of critical region in terms of parabolic cylinder or confluent hypergeometric functions. Results for order parameter, statistics, and thermodynamics match known asymptotics outside critical region. We suggest 2-level and 3-level trap models and find their exact solutions in terms of cut-off negative binomial distribution (that tends to cut-off gamma distribution in continuous limit) and confluent hypergeometric distribution. We introduce a regular refinement scheme for condensate statistics approximations on the basis of infrared universality of higher-order cumulants and method of superposition and show how to model BEC statistics in actual traps. We find that 3-level trap model with matching the first 4 or 5 cumulants is enough to yield remarkably accurate results in whole critical region. We derive exact multinomial expansion for noncondensate occupation distribution and find its high temperature asymptotics (Poisson distribution). We demonstrate that critical exponents and a few known terms of Taylor expansion of universal functions, calculated previously from fitting finite-size simulations within renorm-group theory, can be obtained from presented solutions.
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An exciton is an electron-hole pair bound by attractive Coulomb interaction. Short-lived excitons have been detected by a variety of experimental probes in numerous contexts. An excitonic insulator, a collective state of such excitons, has been more elusive. Here, thanks to Nernst measurements in pulsed magnetic fields, we show that in graphite there is a critical temperature (T = 9.2 K) and a critical magnetic field (B = 47 T) for Bose-Einstein condensation of excitons. At this critical field, hole and electron Landau sub-bands simultaneously cross the Fermi level and allow exciton formation. By quantifying the effective mass and the spatial separation of the excitons in the basal plane, we show that the degeneracy temperature of the excitonic fluid corresponds to this critical temperature. This identification would explain why the field-induced transition observed in graphite is not a universal feature of three-dimensional electron systems pushed beyond the quantum limit.
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