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Register a new userEffects of post-annealing and cobalt co-doping on superconducting properties of (Ca,Pr)Fe2As2 single crystals
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In order to clarify the origin of anomalous superconductivity in (Ca,RE)Fe2As2 system, Pr doped and Pr,Co co-doped CaFe2As2 single crystals were grown by the FeAs flux method. These samples showed two-step superconducting transition with Tc1 = 25~42 K, and Tc2 < 16 K, suggesting that (Ca,RE)Fe2As2 system has two superconducting components. Post-annealing performed for these crystals in evacuated quartz ampoules at various temperatures revealed that post-annealing at ~400{deg}C increased the c-axis length for all samples. This indicates that as-grown crystals have a certain level of strain, which is released by post-annealing at ~400{deg}C. Superconducting properties also changed dramatically by post-annealing. After annealing at 400{deg}C, some of the co-doped samples showed large superconducting volume fraction corresponding to the perfect diamagnetism below Tc2 and high Jc values of 104~105 Acm-2 at 2 K in low field, indicating the bulk superconductivity of (Ca,RE)Fe2As2 phase occurred below Tc2. On the contrary, the superconducting volume fraction above Tc2 was always very small, suggesting that 40 K-class superconductivity observed in this system is originating in the local superconductivity in the crystal.
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Bi$_2$Sr$_{2-x}$La$_x$CuO$_{6+delta}$ (0$leq x leq$1.00) single crystals with high-quality have been grown successfully using the travelling-solvent floating-zone technique. The patterns of X-ray diffraction suggest high crystalline quality of the samples. After post-annealing in flowing oxygen at 600 $^o$C, the crystals show sharp superconducting transitions revealed by AC susceptibility. The hole concentration $p$ is deduced from superconducting transition temperature ($T_c$), which exhibits a linear relation with La doping level $x$. It ranges from the heavily overdoped regime ($p approx$ 0.2) to the extremely underdoped side ($p approx$ 0.08) where the superconductivity is absent. Comparing with the superconducting dome in Bi$_{2+x}$Sr$_{2-x}$CuO$_{6+delta}$ system, the effects from out-of-plane disorders show up in our samples. Besides the La doping level $x$, the superconductivity is also sensitive to the content of oxygen which could be tuned by post-annealing method over the whole doping range. The post-annealing effects on $T_c$ and $p$ for each La doping level are studied, which give some insights on the different nature between overdoped and underdoped regime.
Resistivity and magnetic susceptibility measurements under external pressure were performed on single-crystals NaFe1-xCoxAs (x=0, 0.01, 0.028, 0.075, 0.109). The maximum Tc enhanced by pressure in both underdoped and optimally doped NaFe1-xCoxAs is the same, as high as 31 K. The overdoped sample with x = 0.075 also shows a positive pressure effect on Tc, and an enhancement of Tc by 13 K is achieved under pressure of 2.3 GPa. All the superconducting samples show large positive pressure coefficient on superconductivity, being different from Ba(Fe1-xCox)2As2. However, the superconductivity cannot be induced by pressure in heavily overdoped non-superconducting NaFe0.891Co0.109As. These results provide evidence for that the electronic structure is much different between superconducting and heavily overdoped non-superconducting NaFe1-xCoxAs, being consistent with the observation by angle-resolved photoemission spectroscopy.
The influence of irradiation by electrons with energies of $0.5-2.5$,MeV at temperatures of about $10$,K on the basal-plane resistivity of the YBa$_2$Cu$_3$O$_{7-delta}$ single crystals is investigated in the range from $T_c$ to $300$,K. The resistivity temperature dependence is determined by defects arising due to the irradiation. These defects directly affect the superconducting transition, decreasing $T_c$ and increasing the transition width without significant distortions of its shape. The resulting defects also lead to an increase in the Debye temperature due to a reduction of the anisotropy, and a noticeable increase in the scattering by phonons in the sample. The excess conductivity does not change with the irradiation used.
Single crystals of the LnFeAsO (Ln1111, Ln = Pr, Nd, and Sm) family with lateral dimensions up to 1 mm were grown from NaAs and KAs flux at high pressure. The crystals are of good structural quality and become superconducting when O is partially substituted by F (PrFeAsO1-xFx and NdFeAsO1-xFx) or when Fe is substituted by Co (SmFe1-xCoxAsO). From magnetization measurements, we estimate the temperature dependence and anisotropy of the upper critical field and the critical current density of underdoped PrFeAsO0.7F0.3 crystal with Tc = 25 K. Single crystals of SmFe1-xCoxAsO with maximal Tc up to 16.3 K for x = 0.08 were grown for the first time. From transport and magnetic measurements we estimate the critical fields and their anisotropy, and find these superconducting properties to be quite comparable to the ones in SmFeAsO1-xFx with a much higher Tc of = 50 K. The magnetically measured critical current densities are as high as 109 A/m2 at 2 K up to 7 T, with indication of the usual fishtail effect. The upper critical field estimated from resistivity measurements is anisotropic with slopes of -8.7 T/K (H // ab-plane) and -1.7 T/K (H // c-axis). This anisotropy (= 5) is similar to that in other Ln1111 crystals with various higher Tc s.
Single crystals of RbOs2O6 have been grown from Rb2O and Os in sealed quartz ampoules. The crystal structure has been identified at room temperature as cubic with the lattice constant a = 10.1242(12) A. The anisotropy of the tetrahedral and octahedral networks is lower and the displacement parameters of alkali metal atoms are smaller than for KOs2O6, so the rattling of the alkali atoms in RbOs2O6 is less pronounced. Superconducting properties of RbOs2O6 in the mixed state have been well described within the London approach and the Ginzburg-Landau parameter kappa(0) = 31 has been derived from the reversible magnetization. This parameter is field dependent and changes at low temperatures from kappa = 22 (low fields) to kappa = 31 at H_{c2}. The thermodynamic critical field H_{c}(0) = 1.3 kOe and the superconducting gap 2delta/k_{B}T_{c} = 3.2 have been estimated. These results together with slightly different H_{c2}(T) dependence obtained for crystals and polycrystalline RbOs2O6 proof evidently that this compound is a weak-coupling BCS-type superconductor close to the dirty limit.
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