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Quantum Maxwells Demon in Thermodynamic Cycles

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 Added by H. Dong
 Publication date 2010
  fields Physics
and research's language is English




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We study the physical mechanism of Maxwells Demon (MD) helping to do extra work in thermodynamic cycles, by describing measurement of position, insertion of wall and information erasing of MD in a quantum mechanical fashion. The heat engine is exemplified with one molecule confined in an infinitely deep square potential inserted with a movable solid wall, while the MD is modeled as a two-level system (TLS) for measuring and controlling the motion of the molecule. It is discovered that the the MD with quantum coherence or on a lower temperature than that of the heat bath of the particle would enhance the ability of the whole work substance formed by the system plus the MD to do work outside. This observation reveals that the role of the MD essentially is to drive the whole work substance being off equilibrium, or equivalently working with an effective temperature difference. The elaborate studies with this model explicitly reveal the effect of finite size off the classical limit or thermodynamic limit, which contradicts the common sense on Szilard heat engine (SHE). The quantum SHEs efficiency is evaluated in detail to prove the validity of second law of thermodynamics.



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Converting information into work has during the last decade gained renewed interest as it gives insight into the relation between information theory and thermodynamics. Here we theoretically investigate an implementation of Maxwells demon in a double quantum dot and demonstrate how heat can be converted into work using only information. This is accomplished by continuously monitoring the charge state of the quantum dots and transferring electrons against a voltage bias using a feedback scheme. We investigate the electrical work produced by the demon and find a non-Gaussian work distribution. To illustrate the effect of a realistic charge detection scheme, we develop a model taking into account noise as well as a finite delay time, and show that an experimental realization is feasible with present day technology. Depending on the accuracy of the measurement, the system is operated as an implementation of Maxwells demon or a single-electron pump.
Maxwells demon explores the role of information in physical processes. Employing information about microscopic degrees of freedom, this intelligent observer is capable of compensating entropy production (or extracting work), apparently challenging the second law of thermodynamics. In a modern standpoint, it is regarded as a feedback control mechanism and the limits of thermodynamics are recast incorporating information-to-energy conversion. We derive a trade-off relation between information-theoretic quantities empowering the design of an efficient Maxwells demon in a quantum system. The demon is experimentally implemented as a spin-1/2 quantum memory that acquires information, and employs it to control the dynamics of another spin-1/2 system, through a natural interaction. Noise and imperfections in this protocol are investigated by the assessment of its effectiveness. This realization provides experimental evidence that the irreversibility on a non-equilibrium dynamics can be mitigated by assessing microscopic information and applying a feed-forward strategy at the quantum scale.
We discuss a self-contained spin-boson model for a measurement-driven engine, in which a demon generates work from thermal excitations of a quantum spin via measurement and feedback control. Instead of granting it full direct access to the spin state and to Landauers erasure strokes for optimal performance, we restrict this demons action to pointer measurements, i.e. random or continuous interrogations of a damped mechanical oscillator that assumes macroscopically distinct positions depending on the spin state. The engine can reach simultaneously the power and efficiency benchmarks and operate in temperature regimes where quantum Otto engines would fail.
The dissipation generated during a quasistatic thermodynamic process can be characterised by introducing a metric on the space of Gibbs states, in such a way that minimally-dissipating protocols correspond to geodesic trajectories. Here, we show how to generalize this approach to open quantum systems by finding the thermodynamic metric associated to a given Lindblad master equation. The obtained metric can be understood as a perturbation over the background geometry of equilibrium Gibbs states, which is induced by the Kubo-Mori-Bogoliubov (KMB) inner product. We illustrate this construction on two paradigmatic examples: an Ising chain and a two-level system interacting with a bosonic bath with different spectral densities.
The first direct experimental replication of the Maxwell Demon thought experiment is outlined. The experiment determines the velocity/kinetic energy distribution of the particles in a sample by a novel interpretation of the results from a standard time-of-flight (TOF) small angle neutron scattering (SANS) procedure. Perspex at 293 K was subjected to neutrons at 82.2 K. The key result is a TOF velocity distribution curve that is a direct spatial and time-dependent microscopic probe of the velocity distribution of the Perspex nuclei at 293 K. Having this curve, one can duplicate the Demons approach by selecting neutrons at known kinetic energies. One example is given: namely, two reservoirs -- hot and cold reservoirs -- were generated from the 293 K source without disturbing its original 293 K energy distribution.
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