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A Live Maxwells Demon

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 Added by Debra J. Searles
 Publication date 2019
  fields Physics
and research's language is English




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The first direct experimental replication of the Maxwell Demon thought experiment is outlined. The experiment determines the velocity/kinetic energy distribution of the particles in a sample by a novel interpretation of the results from a standard time-of-flight (TOF) small angle neutron scattering (SANS) procedure. Perspex at 293 K was subjected to neutrons at 82.2 K. The key result is a TOF velocity distribution curve that is a direct spatial and time-dependent microscopic probe of the velocity distribution of the Perspex nuclei at 293 K. Having this curve, one can duplicate the Demons approach by selecting neutrons at known kinetic energies. One example is given: namely, two reservoirs -- hot and cold reservoirs -- were generated from the 293 K source without disturbing its original 293 K energy distribution.



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In the case of fully chaotic systems the distribution of the Poincarerecurrence times is an exponential whose decay rate is the Kolmogorov-Sinai(KS) entropy.We address the discussion of the same problem, the connection between dynamics and thermodynamics,in the case of sporadic randomness,using the Manneville map as a prototype of this class of processes. We explore the possibility of relating the distribution of Poincare recurrence times to `thermodynamics,in the sense of the KS entropy,also in the case of an inverse power law. This is the dynamic property that Zaslavsly [Phys.Today(8), 39(1999)] finds to be responsible for a striking deviation from ordinary statistical mechanics under the form of Maxwells Demon effect. We show that this way of estabi- lishing a connection between thermodynamics and dynamics is valid only in the case of strong chaos. In the case of sporadic randomness, resulting at long times in the Levy diffusion processes,the sensitivity to initial conditions is initially an inverse pow erlaw,but it becomes exponential in the long-time scale, whereas the distribution of Poincare times keeps its inverse power law forever. We show that a nonextensive thermodynamics would imply the Maxwells Demon effect to be determined by memory and thus to be temporary,in conflict with the dynamic approach to Levy statistics. The adoption of heuristic arguments indicates that this effect,is possible, as a form of genuine equilibrium,after completion of the process of memory erasure.
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It is nearly 150 years since Maxwell challenged the validity of the second law of thermodynamics by imagining a tiny creature who could sort the molecules of a gas in such a way that would decrease entropy without exerting any work. The demon has been discussed largely using thought experiments, but it has recently become possible to exert control over nanoscale systems, just as Maxwell imagined, and the status of the second law has become a more practical matter, raising the issue of how measurements manage our ignorance in a way that can be exploited. The framework of stochastic thermodynamics extends macroscopic concepts such as heat, work, entropy and irreversibility to small systems and allows us explore the matter. Some arguments against a successful demon imply a second law that can be suspended indefinitely until we dissipate energy in order to remove the records of his operations. In contrast, under stochastic thermodynamics the demon fails because on average more work is performed upfront in making a measurement than is to be extracted by exploiting the outcome. This requires us to exclude systems and a demon that evolve under what might be termed self-sorting dynamics, and we reflect on the constraints on control that this implies while still working within a thermodynamic framework.
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