In this research we studied the relationship between the optical conductivity Ϭop and
photon energy (hν), the absorbance coefficient (α), transmittance (T), the refractive index
(no), and the real part and imaginary part of dielectric constant (εr,
εi), the spinning velocity
of deposition device (v), for a specific wave length (600nm), for a pure thin film prepared
from an organic polymer material, Polystyrene (PS), by spin coating technique, on three
velocities ( 1000-2000-3000)RPM, in room temperature and 1atm.
It was shown that the PS film is a transmittive film with a transmittance values
reach ( 85 – 90 )% in the infrared region, and the optical conductivity Ϭop increased with
the photon energy, and for the velocity 1000RPM it took the highest value ( 1.67 X
1014 )1/sec, at the photon energy (hν =3.1 ev) and the wave length ( λ= 400nm ),
which means that the optical conductivity Ϭop is active in the visible region, and also it
decreases with the spinning velocity.
The values of energy gap for allowed direct transitions were (2.5ev), (2.4ev), (2.3ev)
for the films prepared on 1000RPM, 2000RPM, 3000RPM, and for the forbidden direct
transitions were (2.3ev), (2.2ev), (2.1ev) respectively .
The biggest value of Urbach energy Eu was (163mev) on the velocity 1000RPM and
the lowest value was (109mev) on the velocity 3000RPM.
This research depends on treating different waste polystyrenes like; general
purpose polystyrene, foamed polystyrene (styropor), high impact, and rubber
modified polystyrene (HIPS) by thermal cracking in order to have liquid
products which might b
e used as additives to gasoline. These products are
essentially aromatics and aromatic olefines of a high octane number > ١٠٠, free
from sulfer and lead, and they are able to be used as octane boosters. It is
possible to redistill these products in order to have styene monomer with a
yield of ٤٠ - ٤٣٪, which can be used after that for polymerisation purposes.
polystyrene
بولي ستيرين
نفايات البولي ستيرين المختلفة
نقطة الإيتيلين المختلطة
نقطة الوميض
قرينة اليود
رقم الأوكتان
التكسير الحراري لنفايات البولي ستيرين
التكسير الحراري لنفايات البولي ستيرين باستخدام حفاز « البنتونايت »
Different waste polystyren
Mixed aniline point
Flash point
Indine index
Octane number
Thermal cracking of rubber polystyren
المزيد..