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The Microscopic Model of BiFeO$_3$

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 نشر من قبل Randy Fishman
 تاريخ النشر 2017
  مجال البحث فيزياء
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 تأليف Randy S. Fishman




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Many years and great effort have been spent constructing the microscopic model for the room temperature multiferroic BiFeO3 However, earlier models implicitly assumed that the cycloidal wavevector q was confined to one of the three-fold symmetric axis in the hexagonal plane normal to the electric polarization. Because recent measurements indicate that q can be rotated by a magnetic field, it is essential to properly treat the anisotropy that confines q at low fields. We show that the anisotropy energy $-K_3 S^6 sin^6 theta cos 6 phi $ confines the wavevectors q to the three-fold axis $phi =0$ and $+-2 pi/3$ within the hexagonal plane with $theta = pi /2$.



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The present manuscript completes the study presented in two recent research articles [K. Koumpouras and I. Galanakis, textit{J. Magn. Magn. Mater.} 323, 2328 (2011); textit{ibid}, textit{J. Spintron. Magn. Nanomater.} 1, in press]. Preliminary first- principles calculations using the QUANTUM-espresso package [P. Giannozzi et al textit{J. Phys.:Condens. Matter} 21, 395502 (2009)] on the magnetic behavior of ultra-thin epitaxial multilayers between the BiFeO$_3$ magnetoelectric compound and various types of spacers are presented. As spacer we have considered i) InP semiconductor, ii) Fe which is a ferromagnet, and iii) metallic V. In all cases under study the growth axis of the multilayer was the [001]. Our results indicate that the magnetic properties are seriously downgraded for the ultrathin BiFeO$_3$ multilayers independent of the nature of the spacer and in some cases under study magnetism even vanishes. More extensive calculations are needed to establish a more clear view of the physical properties of the interfaces involving the BiFeO$_3$ compound.
163 - Randy S. Fishman 2013
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