ترغب بنشر مسار تعليمي؟ اضغط هنا

Wetting transition of water on graphite and other surfaces

64   0   0.0 ( 0 )
 نشر من قبل Silvina Gatica Dr
 تاريخ النشر 2004
  مجال البحث فيزياء
والبحث باللغة English




اسأل ChatGPT حول البحث

A wetting transition occurs when the contact angle of a liquid drop on a surface changes from a nonzero value to zero. Such a transition has never been observed for water on any solid surface. This paper discusses the value of the temperature T_w at which the transition should occur for water on graphite. A simple model, previously used for nonpolar fluids, predicts the value of $T_w$ as a function of the well-depth D of the adsorption potential. While $D$ is not well known for the case of water/graphite, the model implies that T_w is likely to fall in the range 350 to 500 K. Experimental search for this transition is warranted. Water wetting transition temperatures on other surfaces are also discussed.



قيم البحث

اقرأ أيضاً

143 - S. Sarkar , S. Patra , N. Gayathri 2009
The relation between the contact angle of a liquid drop and the morphological parameters of self-affine solid surfaces have been investigated. We show experimentally that the wetting property of a solid surface crucially depends on the surface morpho logical parameters such as: (1) root mean square (rms) roughness $sigma$, (2) in-plane roughness correlation length $xi$ and (3) roughness exponent $alpha$ of the self-affine surface. We have shown that the contact angle monotonically decreases with the increase in the rms local surface slope $rho$ ($propto sigma/xi^alpha$) for the cases where the liquid wets the crevices of the surface upon contact. We have shown that the same solid surface can be made hydrophobic or hydrophilic by merely tuning these self-affine surface morphological parameters.
We present a combined experimental and theoretical study of the self-diffusion of ammonia on exfoliated graphite. Using neutron time-of-flight spectroscopy we are able to resolve the ultrafast diffusion process of adsorbed ammonia, NH$_3$, on graphit e. Together with van der Waals corrected density functional theory calculations we show that the diffusion of NH$_3$ follows a hopping motion on a weakly corrugated potential energy surface with an activation energy of about 4 meV which is particularly low for this type of diffusive motion. The hopping motion includes further a significant number of long jumps and the diffusion constant of ammonia adsorbed on graphite is determined with $D=3.9 cdot 10^{-8}~mbox{m}^2 /mbox{s}$ at 94 K.
121 - D. Alfe` , M. J. Gillan 2006
Density functional theory (DFT) is widely used in surface science, but gives poor accuracy for oxide surface processes, while high-level quantum chemistry methods are hard to apply without losing basis-set quality. We argue that quantum Monte Carlo t echniques allow these difficulties to be overcome, and we present diffusion Monte Carlo results for the formation energy of the MgO(001) surface and the adsorption energy of H$_2$O on this surface, using periodic slab geometry. The results agree well with experiment. We note other oxide surface problems where these techniques could yield immediate progress.
We present a x-ray dichroism study of graphite surfaces that addresses the origin and magnitude of ferromagnetism in metal-free carbon. We find that, in addition to carbon $pi$ states, also hydrogen-mediated electronic states exhibit a net spin polar ization with significant magnetic remanence at room temperature. The observed magnetism is restricted to the top $approx$10 nm of the irradiated sample where the actual magnetization reaches $ simeq 15$ emu/g at room temperature. We prove that the ferromagnetism found in metal-free untreated graphite is intrinsic and has a similar origin as the one found in proton bombarded graphite.
145 - M. Moaied , J. V. Alvarez , 2014
We calculate the electronic structure and magnetic properties of hydrogenated graphite surfaces using van der Waals density functional theory (DFT) and model Hamiltonians. We find, as previously reported, that the interaction between hydrogen atoms o n graphene favors adsorption on different sublattices along with an antiferromagnetic coupling of the induced magnetic moments. On the contrary, when hydrogenation takes place on the surface of graphene multilayers or graphite (Bernal stacking), the interaction between hydrogen atoms competes with the different adsorption energies of the two sublattices. This competition may result in all hydrogen atoms adsorbed on the same sublattice and, thereby, in a ferromagnetic state for low concentrations. Based on the exchange couplings obtained from the DFT calculations, we have also evaluated the Curie temperature by mapping this system onto an Ising-like model with randomly located spins. Remarkably, the long-range nature of the magnetic coupling in these systems makes the Curie temperature size dependent and larger than room temperature for typical concentrations and sizes.
التعليقات
جاري جلب التعليقات جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
mircosoft-partner

هل ترغب بارسال اشعارات عن اخر التحديثات في شمرا-اكاديميا