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تسجيل مستخدم جديدInfluence of dopant concentration on the structure and physical properties of Nd$_{1-x}$Pb$_{x}$MnO$_{3}$ single crystals
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The structure of Nd$_{1-x}$Pb$_{x}$MnO$_{3}$ crystals is determined by single crystal X-ray diffraction. Substitution of Pb at the Nd site results in structural phase change from tetragonal (x = 0.25) to cubic (x = 0.37). These changes are attributed to the progressive removal of inter-octahedral tilting and minimization of the octahedral distortion leading to a higher symmetry as doping concentration increases. While the unit cell volume of tetragonal structure ($it{P4/mmm}$) is comparable to that of parent NdMnO$_{3}$, the volume of cubic unit cell ($it{Pmbar{3}m}$) is doubled. Electron diffraction patterns support these results and rule out the possibility of twinning. Changes in transport properties as a function of temperature at different doping levels are in accordance with the observed structural changes. It is noticed that $it{T_{c}}$ and $it{T_{MI}}$ increase with x.
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