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Molecular cations are present in various astronomical environments, most notably in cometary atmospheres and tails where sunlight produces exceptionally bright near-UV to visible transitions. Such cations typically have longer-wavelength and brighter electronic emission than their corresponding neutrals. A robust understanding of their near-UV to visible properties would allow these cations to be used as tools for probing the local plasma environments or as tracers of neutral gas in cometary environments. However, full spectral models are not possible for characterization of small, oxygen containing molecular cations given the body of molecular data currently available. The five simplest such species (H2O+, CO+2 , CO+, OH+, and O+2 ) are well characterized in some spectral regions but are lacking robust reference data in others. Such knowledge gaps hinder fully quantitative models of cometary spectra, specifically, hindering accurate estimates of physical-chemical processes originating with the most common molecules in comets. Herein the existing spectral data are collected for these molecules and highlight the places where future work is needed, specifically where the lack of such data would greatly enhance the understanding of cometary evolution.
We study the visible and near-infrared (NIR) spectral properties of different ACO populations and compare them to the independently determined properties of comets. We select our ACOs sample based on published dynamical criteria and present our own
Filamentary enstatite crystals are found in interplanetary dust particles of likely cometary origin but are very rare or absent in meteorites. Crystallographic characteristics of filamentary enstatites indicate that they condensed directly from vapor
We present the detection of new cometary X-ray emission lines in the 1.0 to 2.0 keV range using a sample of comets observed with the Chandra X-ray observatory and ACIS spectrometer. We have selected 5 comets from the Chandra sample with good signal-t
Molecular oxygen has been detected in the coma of comet 67P/Churyumov-Gerasimenko with abundances in the 1-10% range by the ROSINA-DFMS instrument on board the Rosetta spacecraft. Here we find that the radiolysis of icy grains in low-density environm
Recently the ROSINA mass spectrometer suite on board the European Space Agencys Rosetta spacecraft discovered an abundant amount of molecular oxygen, O2, in the coma of Jupiter family comet 67P/Churyumov-Gerasimenko of O2/H2O = 3.80+/-0.85%. It could