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The atmosphere of Titan, the largest moon of Saturn, is rich in organic molecules, and it has been suggested that the moon may serve as an analog for the pre-biotic Earth due to its highly reducing chemistry and existence of global hazes. Photochemical models of Titan have predicted the presence of propadiene (historically referred to as allene), CH$_{2}$CCH$_{2}$, an isomer of the well-measured propyne (also called methylacetylene) CH$_{3}$CCH, but its detection has remained elusive due to insufficient spectroscopic knowledge of the molecule - which has recently been remedied with an updated spectral line list. Here we present the first unambiguous detection of the molecule in any astronomical object, observed with the Texas Echelle Cross Echelle Spectrograph (TEXES) on the NASA Infrared Telescope Facility (IRTF) in July 2017. We model its emission line near 12 $mu$m and measure a volume mixing ratio (VMR) of (6.9 $pm$ 0.8) $times$10$^{-10}$ at 175 km, assuming a vertically increasing abundance profile as predicted in photochemical models. Cassini measurements of propyne made during April 2017 indicate that the abundance ratio of propyne to propadiene is 8.2$pm$1.1 at the same altitude. This initial measurement of the molecule in Titans stratosphere paves the way towards constraining the amount of atomic hydrogen available on Titan, as well as future mapping of propadiene on Titan from 8 meter and larger ground based observatories, and future detection on other planetary bodies.
Thanks to the Cassini-Huygens mission, Titan, the pale orange dot of Pioneer and Voyager encounters has been revealed to be a dynamic, hydrologically-shaped, organic-rich ocean world offering unparalleled opportunities to explore prebiotic chemistry.
We report the first detection on Titan of the small cyclic molecule cyclopropenylidene (c-C3H2) from high sensitivity spectroscopic observations made with the Atacama Large Millimeter/sub-millimeter Array (ALMA). Multiple lines of cyclopropenylidene
We report the first spectroscopic detection of ethyl cyanide (C$_2$H$_5$CN) in Titans atmosphere, obtained using spectrally and spatially resolved observations of multiple emission lines with the Atacama Large Millimeter/submillimeter array (ALMA). T
Conditions on Saturns moon Titan suggest dust devils, which are convective, dust-laden plumes, may be active. Although the exact nature of dust on Titan is unclear, previous observations confirm an active aeolian cycle, and dust devils may play an im
Winds in Titans lower and middle atmosphere have been determined by a variety of techniques, including direct measurements from the Huygens Probe over 0-150 km, Doppler shifts of molecular spectral lines in the optical, thermal infrared and mm ranges