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We use the recently-proposed emph{compressible cell} Ising-like model [Phys. Rev. Lett. textbf{120}, 120603 (2018)] to estimate the ratio between thermal expansivity and specific heat (the Gruneisen parameter $Gamma$) in supercooled water. Near the critical pressure and temperature, $Gamma$ increases. The $Gamma$ value diverges near the pressure-induced finite-$T$ critical end-point [Phys. Rev. Lett. textbf{104}, 245701 (2010)] and quantum critical points [Phys. Rev. Lett. textbf{91}, 066404 (2003)], which indicates that two energy scales are governing the system. This enhanced behavior of $Gamma$ is caused by the coexistence of high- and low-density liquids [Science textbf{358}, 1543 (2017)]. Our findings support the proposed liquid-liquid critical point in supercooled water in the No-Mans Land regime, and indicates possible applications of this model to other systems.
Recent computational studies have reported evidence of a metastable liquid-liquid phase transition (LLPT) in molecular models of water under deeply supercooled conditions. A competing hypothesis suggests, however, that non-equilibrium artifacts assoc
Deeply supercooled water exhibits complex dynamics with large density fluctuations, ice coarsening and characteristic time scales extending from picoseconds to milliseconds. Here, we discuss implications of these time scales as they pertain to two-ph
The well-known classical nucleation theory (CNT) for the free energy barrier towards formation of a nucleus of critical size of the new stable phase within the parent metastable phase fails to take into account the influence of other metastable phase
The Gruneisen ratio ($Gamma$), i.e.,the ratio of the linear thermal expansivity to the specific heat at constant pressure, quantifies the degree of anharmonicity of the potential governing the physical properties of a system. While $Gamma$ has been i
Water shows intriguing thermodynamic and dynamic anomalies in the supercooled liquid state. One possible explanation of the origin of these anomalies lies in the existence of a metastable liquid-liquid phase transition (LLPT) between two (high and lo