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High levels of deuterium fraction in N$_2$H$^+$ are observed in some pre-stellar cores. Single-zone chemical models find that the timescale required to reach observed values ($D_{rm frac}^{{rm N}_2{rm H}^+} equiv {rm N}_2{rm D}^+/{rm N}_2{rm H}^+ gtrsim 0.1$) is longer than the free-fall time, possibly ten times longer. Here, we explore the deuteration of turbulent, magnetized cores with 3D magnetohydrodynamics simulations. We use an approximate chemical model to follow the growth in abundances of N$_2$H$^+$ and N$_2$D$^+$. We then examine the dynamics of the core using each tracer for comparison to observations. We find that the velocity dispersion of the core as traced by N$_2$D$^+$ appears slightly sub-virial compared to predictions of the Turbulent Core Model of McKee & Tan, except at late times just before the onset of protostar formation. By varying the initial mass surface density, the magnetic energy, the chemical age, and the ortho-to-para ratio of H$_2$, we also determine the physical and temporal properties required for high deuteration. We find that low initial ortho-to-para ratios ($lesssim 0.01$) and/or multiple free-fall times ($gtrsim 3$) of prior chemical evolution are necessary to reach the observed values of deuterium fraction in pre-stellar cores.
High levels of deuterium fractionation of $rm N_2H^+$ (i.e., $rm D_{frac}^{N_2H^+} gtrsim 0.1$) are often observed in pre-stellar cores (PSCs) and detection of $rm N_2D^+$ is a promising method to identify elusive massive PSCs. However, the physical
Clouds of high infrared extinction are promising sites of massive star/cluster formation. A large number of cloud cores discovered in recent years allows investigation of possible evolutionary sequence among cores in early phases. We have conducted a
We report the detection of D2CO in a sample of starless dense cores, in which we previously measured the degree of CO depletion. The deuterium fractionation is found extremely high, [D2CO]/[H2CO] ~ 1-10 %, similar to that reported in low-mass protost
The deuterium fraction [N$_2$D$^+$]/[N$_2$H$^+$], may provide information about the ages of dense, cold gas structures, important to compare with dynamical models of cloud core formation and evolution. Here we introduce a complete chemical network wi
We have performed a pointed survey of N2D+ 2-1 and N2D+ 3-2 emission toward 64 N2H+-bright starless and protostellar cores in the Perseus molecular cloud using the Arizona Radio Observatory Submillimeter Telescope and Kitt Peak 12 m telescope. We fin