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A Computationally Assisted Spectroscopic Technique to measure secondary electron emission coefficients ($gamma$-CAST) in capacitively-coupled radio-frequency plasmas is proposed. This non-intrusive, sensitive diagnostic is based on a combination of Phase Resolved Optical Emission Spectroscopy and particle-based kinetic simulations. In such plasmas (under most conditions in electropositive gases) the spatio-temporally resolved electron-impact excitation/ionization rate features two distinct maxima adjacent to each electrode at different times within each RF period. While one maximum is the consequence of the energy gain of electrons due to sheath expansion, the second maximum is produced by secondary electrons accelerated towards the plasma bulk by the sheath electric field at the time of maximum voltage drop across the adjacent sheath. Due to these different excitation/ionization mechanisms, the ratio of the intensities of these maxima is very sensitive to the secondary electron emission coefficient $gamma$. This sensitvity, in turn, allows $gamma$ to be determined by comparing experimental excitation profiles and simulation data obtained with various $gamma$-coefficients. The diagnostic, tested here in a geometrically symmetric argon discharge, yields an effective secondary electron emission coefficient of $gamma = 0.066 pm 0.01$ for stainless steel electrodes.
A bounded plasma where the electrons impacting the walls produce more than one secondary on average is studied via particle-in-cell simulation. It is found that no classical Debye sheath or space-charge limited sheath exists. Ions are not drawn to th
In most PIC/MCC simulations of radio frequency capacitively coupled plasmas (CCPs) several simplifications are made: (i) fast neutrals are not traced, (ii) heavy particle induced excitation and ionization are neglected, (iii) secondary electron emiss
Radio frequency (RF) waves can provide heating, current and flow drive, as well as instability control for steady state operations of fusion experiments. A particle simulation model has been developed in this work to provide a first-principles tool f
The kinetic origin of resonance phenomena in capacitively coupled radio frequency plasmas is discovered based on particle-based numerical simulations. The analysis of the spatio-temporal distributions of plasma parameters such as the densities of hot
Scattering phenomena between charged particles and highly excited Rydberg atoms are of critical importance in many processes in plasma physics and astrophysics. While a Maxwell-Boltzmann (MB) energy distribution for the charged particles is often ass