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The apparition of bright comets C/2012 F6 (Lemmon) and C/2014 Q2 (Lovejoy) in March-April 2013 and January 2015, combined with the improved observational capabilities of submillimeter facilities, offered an opportunity to carry out sensitive compositional and isotopic studies of the volatiles in their coma. We observed comet Lovejoy with the IRAM 30m telescope between 13 and 26 January 2015, and with the Odin submillimeter space observatory on 29 January - 3 February 2015. We detected 22 molecules and several isotopologues. The H$_2^{16}$O and H$_2^{18}$O production rates measured with Odin follow a periodic pattern with a period of 0.94 days and an amplitude of ~25%. The inferred isotope ratios in comet Lovejoy are $^{16}$O/$^{18}$O = 499 $pm$ 24 and D/H = 1.4 $pm$ 0.4 $times 10^{-4}$ in water, $^{32}$S/$^{34}$S = 24.7 $pm$ 3.5 in CS, all compatible with terrestrial values. The ratio $^{12}$C/$^{13}$C = 109 $pm$ 14 in HCN is marginally higher than terrestrial and $^{14}$N/$^{15}$N = 145 $pm$ 12 in HCN is half the Earth ratio. Several upper limits for D/H or 12C/13C in other molecules are reported. From our observation of HDO in comet C/2014 Q2 (Lovejoy), we report the first D/H ratio in an Oort Cloud comet that is not larger than the terrestrial value. On the other hand, the observation of the same HDO line in the other Oort-cloud comet, C/2012 F6 (Lemmon), suggests a D/H value four times higher. Given the previous measurements of D/H in cometary water, this illustrates that a diversity in the D/H ratio and in the chemical composition, is present even within the same dynamical group of comets, suggesting that current dynamical groups contain comets formed at very different places or times in the early solar system.
HCN J=1-0 emission from the long-period comet C/2013 R1 (Lovejoy) was observed from the Onsala Space Observatory on multiple occasions during the month before its perihelion passage on December 22, 2013. We report detections for seven different dates
A spectral survey in the 1 mm wavelength range was undertaken in the long-period comets C/2012 F6 (Lemmon) and C/2013 R1 (Lovejoy) using the 30 m telescope of the Institut de radioastronomie millimetrique (IRAM) in April and November-December 2013. W
Results are presented from the first cometary observations using the Atacama Large Millimeter/Submillimeter Array (ALMA), including measurements of the spatially-resolved distributions of HCN, HNC, H$_2$CO and dust within the comae of two comets: C/2
We present molecular observations carried out with the IRAM 30m telescope at wavelengths around 1.15 mm towards the Oort cloud comets C/2012 S1 (ISON) and C/2013 R1 (Lovejoy) when they were at 0.6 and 1 au, respectively, from the Sun. We detect HCN,
Comet composition provides critical information on the chemical and physical processes that took place during the formation of the Solar system. We report here on millimetre spectroscopic observations of the long-period bright comet C/2014 Q2 (Lovejo