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تسجيل مستخدم جديدFluctuation-dissipation relation between shear stress relaxation modulus and shear stress autocorrelation function revisited
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The shear stress relaxation modulus $G(t)$ may be determined from the shear stress $tau(t)$ after switching on a tiny step strain $gamma$ or by inverse Fourier transformation of the storage modulus $G^{prime}(omega)$ or the loss modulus $G^{primeprime}(omega)$ obtained in a standard oscillatory shear experiment at angular frequency $omega$. It is widely assumed that $G(t)$ is equivalent in general to the equilibrium stress autocorrelation function $C(t) = beta V langle delta tau(t) delta tau(0)rangle$ which may be readily computed in computer simulations ($beta$ being the inverse temperature and $V$ the volume). Focusing on isotropic solids formed by permanent spring networks we show theoretically by means of the fluctuation-dissipation theorem and computationally by molecular dynamics simulation that in general $G(t) = G_{eq} + C(t)$ for $t > 0$ with $G_{eq}$ being the static equilibrium shear modulus. A similar relation holds for $G^{prime}(omega)$. $G(t)$ and $C(t)$ must thus become different for a solid body and it is impossible to obtain $G_{eq}$ directly from $C(t)$.
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