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Water in outflows from protostars originates either as a result of gas-phase synthesis from atomic oxygen at T > 200 K, or from sputtered ice mantles containing water ice. We aim to quantify the contribution of the two mechanisms that lead to water in outflows, by comparing observations of gas-phase water to methanol (a grain surface product) towards three low-mass protostars in NGC1333. In doing so, we also quantify the amount of methanol destroyed in outflows. To do this, we make use of JCMT and Herschel-HIFI data of H2O, CH3OH and CO emission lines and compare them to RADEX non-LTE excitation simulations. We find up to one order of magnitude decrease in the column density ratio of CH3OH over H2O as the velocity increases in the line wings up to ~15 km/s. An independent decrease in X(CH3OH) with respect to CO of up to one order of magnitude is also found in these objects. We conclude that gas-phase formation of H2O must be active at high velocities (above 10 km/s, relative to the source velocity) to re-form the water destroyed during sputtering. In addition, the transition from sputtered water at low velocities to formed water at high velocities must be gradual. We place an upper limit of two orders of magnitude on the destruction of methanol by sputtering effects.
Methanol and complex organic molecules have been found in cold starless cores, where a standard warm-up scenario would not work because of the absence of heat sources. A recent chemical model attributed the presence of methanol and large organics to
Recent water line observations toward several low-mass protostars suggest low water gas fractional abundances in the inner warm envelopes. Water destruction by X-rays has been proposed to influence the water abundances in these regions, but the detai
In the framework of the Water in Star-forming regions with Herschel (WISH) key program, maps in water lines of several outflows from young stars are being obtained, to study the water production in shocks and its role in the outflow cooling. This pap
Context: Outflows are an important part of the star formation process as both the result of ongoing active accretion and one of the main sources of mechanical feedback on small scales. Water is the ideal tracer of these effects because it is present
Within low-mass star formation, water vapor plays a key role in the chemistry and energy balance of the circumstellar material. The Herschel Space Observatory will open up the possibility to observe water lines originating from a wide range of excita