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Magnetization, neutron diffraction and X-ray diffraction of Zn doped MnV2O4 as a function of temperature have been measured and the critical exponents and magnetocaloric effect of this system have been estimated. It is observed, that with increase in Zn substitution the noncollinear orientation of Mn spins with the V spins decreases which effectively leads to the decrease of structural transition temperature more rapidly than Curie temperature. It has been shown that the obtained values of {beta}, {gamma} and {delta} from different methods match very well. These values do not belong to universal class and the values are in between the 3D Heisenberg model and mean field interaction model. The magnetization data follow the scaling equation and collapse into two branches indicating that the calculated critical exponents and critical temperature are unambiguous and intrinsic to the system. The observed double peaks in magneto-caloric curve of Mn0.95Zn0.05V2O4 is due to the strong distortion of VO6 octahedra.
We report the structural and magnetic properties of a new class of cobaltates with the chemical formula (BaSr)4-xLa2xCo4O15 (x = 0, 0.5 and 1). These compounds crystallize in a hexagonal structure in which cobalt ions are distributed among two distin
We report on the synthesis of a new $gamma$-phase of the spin $S$~=~$frac{3}{2}$ compound SrCo$_2$(PO$_4$)$_2$ together with a detailed structural, magnetic and thermodynamic properties. The $gamma$-phase of SrCo$_2$(PO$_4$)$_2$ crystallizes in a tri
We have synthesized single crystals of CeZnAl$_3$, which is a new member of the family of the Ce-based intermetallics Ce$TX_3$ ($T$ = transition metal, $X$= Si, Ge, Al), crystallizing in the non-centrosymmetric tetragonal BaNiSn$_3$-type structure. M
The lacunar spinel GeV4S8 undergoes orbital and ferroelectric ordering at the Jahn-Teller transition around 30 K and exhibits antiferromagnetic order below about 14 K. In addition to this orbitally driven ferroelectricity, lacunar spinels are an inte
We report a comprehensive investigation of the triple perovskite iridate Ba$_{3}$CoIr$_{2}$O$_{9}$. Stabilizing in the hexagonal $P6_{3}/mmc$ symmetry at room temperature, this system transforms to a monoclinic $C2/c$ symmetry at the magnetic phase t