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Verification of {Gamma}$_{7}$ symmetry assignment for the top valence band of ZnO by magneto-optical studies of the free A exciton state

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 نشر من قبل Lu Ding
 تاريخ النشر 2012
  مجال البحث فيزياء
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The circularly-polarized and angular-resolved magneto-photoluminescence spectroscopy was carried out to study the free A exciton 1S state in wurtzite ZnO at 5 K.

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We studied the circular polarization and angular dependences of the magneto-photoluminescence spectra of the free A-exciton 1S state in wurtzite ZnO at T = 5 K. The circular polarization properties of the spectra clearly indicate that the top valence band has Gamma_7 symmetry. The out-of-plane component of the magnetic field, which is parallel to the samples c axis, leads to linear Zeeman splitting of both the dipole-allowed Gamma_5 exciton state and the weakly allowed Gamma_1/Gamma_2 exciton states. The in-plane field, which is perpendicular to the c axis, increases the oscillator strength of the weak Gamma_1/Gamma_2 states by forming a mixed exciton state.
The uniaxial stress dependence of the band structure and the exciton-polariton transitions in wurtzite ZnO is thoroughly studied using modern first-principles calculations based on the HSE+G0W0 approach, k p modeling using the deformation potential f ramework, and polarized photoluminescence measurements. The ordering of the valence bands [A(G7), B(G9), C(G7)] is found to be robust even for high uniaxial and biaxial strains. Theoretical results for the uniaxial pressure coefficients and splitting rates of the A, B, and C valence bands and their optical transitions are obtained including the effects of the spin-orbit interaction. The excitonic deformation potentials are derived and the stress rates for hydrostatic pressure are determined based on the results for uniaxial and biaxial stress. In addition, the theory for the stress dependence of the exchange interaction and longitudinal-transversal splitting of the exciton-polaritons is developed using the basic exciton functions of the quasi-cubic approximation and taking the interaction between all exciton states into account. It is shown that the consideration of these effects is crucial for an accurate description of the stress dependence of the optical spectra in ZnO. The theoretical results are compared to polarized photoluminescence measurements of different ZnO substrates as function of uniaxial pressure and experimental values reported in the literature demonstrating an excellent agreement with the computed pressure coefficients.
We present a far-infrared magneto-optical study of the gapped nodal-line semimetal ZrSiS in magnetic fields $B$ up to 7 T. The observed field-dependent features, which represent intra- (cyclotron resonance) and interband transitions, develop as $sqrt {B}$ in increasing field and can be consistently explained within a simple 2D Dirac band model with a gap of 26 meV and an averaged Fermi velocity of $3times10^{5}$ m/s. This indicates a rather narrow distribution of these parameters along the in-plane portions of the nodal line in the Brillouin zone. A field-induced feature with an energy position that does not depend on $B$ is also detected in the spectra. Possible origins of this feature are discussed.
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