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Beyond Tanners Law: Crossover between Spreading Regimes of a Viscous Droplet on an Identical Film

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 نشر من قبل Thomas Salez
 تاريخ النشر 2012
  مجال البحث فيزياء
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We present results on the leveling of polymer microdroplets on thin films prepared from the same material. In particular, we explore the crossover from a droplet spreading on an infinitesimally thin film (Tanners law regime) to that of a droplet leveling on a film thicker than the droplet itself. In both regimes, the droplets excess surface area decreases towards the equilibrium configuration of a flat liquid film, but with a different power law in time. Additionally, the characteristic leveling time depends on molecular properties, the size of the droplet, and the thickness of the underlying film. Flow within the film makes this system fundamentally different from a droplet spreading on a solid surface. We thus develop a theoretical model based on thin film hydrodynamics that quantitatively describes the observed crossover between the two leveling regimes.



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