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We introduce a new thermochemical kinetics and photochemical model. We use high-temperature bidirectional reaction rates for important H, C, O and N reactions (most importantly for CH$_4$ to CO interconversion), allowing us to attain thermochemical equilibrium, deep in an atmosphere, purely kinetically. This allows ab initio chemical modeling of an entire atmosphere, from deep-atmosphere thermochemical equilibrium to the photochemically dominated regime. We use our model to explore the atmospheric chemistry of cooler ($T_{eff} < 10^3$ K) extrasolar giant planets. In particular, we choose to model the nearby hot Neptune GJ436b, the only planet in this temperature regime for which spectroscopic measurements and estimates of chemical abundances now exist. Recent {it Spitzer} measurements with retrieval have shown that methane is driven strongly out of equilibrium and is deeply depleted on the dayside of GJ 436b, whereas quenched carbon monoxide is abundant. This is surprising because GJ 436b is cooler than many of the heavily irradiated hot Jovians and thermally favorable for CH$_4$, and thus requires an efficient mechanism for destroying it. We include realistic estimates of ultraviolet flux from the parent dM star GJ 436, to bound the direct photolysis and photosensitized depletion of CH$_4$. While our models indicate fairly rich disequilibrium conditions are likely in cooler exoplanets over a range of planetary metallicities, we are unable to generate the conditions for substantial CH$_4$ destruction. One possibility is an anomalous source of abundant H atoms between 0.01-1 bars (which attack CH$_4$), but we cannot as yet identify an efficient means to produce these hot atoms.
In order to understand the exoplanet, you need to understand its parent star. Astrophysical parameters of extrasolar planets are directly and indirectly dependent on the properties of their respective host stars. These host stars are very frequently
The extrasolar planets (EPs) so far detected are very different to the planets in our own Solar System. Many of them have Jupiter-like masses and close-in orbits (the so-called hot planets, HPs), with orbital periods of only a few days. In this paper
Stellar radiation has conservatively been used as the key constraint to planetary habitability. We review here the effects of tides, exerted by the host star on the planet, on the evolution of the planetary spin. Tides initially drive the rotation pe
The search for extrasolar rocky planets has already found the first transiting rocky super-Earth, Corot 7b, with a surface temperature that allows for magma oceans. Here we ask if we could distinguish rocky planets with recent major volcanism by remo
We revisit the tidal stability of extrasolar systems harboring a transiting planet and demonstrate that, independently of any tidal model, none but one (HAT-P-2b) of these planets has a tidal equilibrium state, which implies ultimately a collision of