We show that the charge and thermal transport measurements on ultraclean crystals of URu2Si2 reveal a number of unprecedented superconducting properties. The uniqueness is best highlighted by the peculiar field dependence of thermal conductivity including the first order transition at Hc2 with a reduction of entropy flow. This is a consequence of multi-band superconductivity with compensated electronic structure in the hidden order state of this system. We provide strong evidence for a new type of unconventional superconductivity with two distinct gaps having different nodal topology.
When a superconductor is heated above its critical temperature $T_c$, macroscopic coherence vanishes, leaving behind droplets of thermally fluctuating Cooper pair. This superconducting fluctuation effect above $T_c$ has been investigated for many dec
ades and its influence on the transport, thermoelectric and thermodynamic quantities in most superconductors is well understood by the standard Gaussian fluctuation theories. The transverse thermoelectric (Nernst) effect is particularly sensitive to the fluctuations, and the large Nernst signal found in the pseudogap regime of the underdoped high-$T_c$ cuprates has raised much debate on its connection to the origin of superconductivity. Here we report on the observation of a colossal Nernst signal due to the superconducting fluctuations in the heavy-fermion superconductor URu$_2$Si$_2$. The Nernst coefficient is enhanced by as large as one million times over the theoretically expected value within the standard framework of superconducting fluctuations. This, for the first time in any known material, results in a sizeable thermomagnetic figure of merit approaching unity. Moreover, contrary to the conventional wisdom, the enhancement in the Nernst signal is more significant with the reduction of the impurity scattering rate. This anomalous Nernst effect intimately reflects the highly unusual superconducting state embedded in the so-called hidden-order phase of URu$_2$Si$_2$. The results invoke possible chiral or Berry-phase fluctuations originated from the topological aspect of this superconductor, which are associated with the effective magnetic field intrinsically induced by broken time-reversal symmetry of the superconducting order parameter.
The superconducting gap structure of recently discovered heavy fermion superconductor PrOs4Sb12 was investigated by using thermal transport measurements in magnetic field rotated relative to the crystal axes. We demonstrate that a novel change in the
symmetry of the superconducting gap function occurs deep inside the superconducting state, giving a clear indication of the presence of two distinct superconducting phases with twofold and fourfold symmetries. We infer that the gap functions in both phases have a point node singularity, in contrast to the familiar line node singularity observed in almost all unconventional superconductors.
We have performed the $^{125}$Te-nuclear magnetic resonance (NMR) measurement in the field along the $b$ axis on the newly discovered superconductor UTe$_2$, which is a candidate of a spin-triplet superconductor. The nuclear spin-lattice relaxation r
ate divided by temperature $1/T_1T$ abruptly decreases below a superconducting (SC) transition temperature $T_c$ without showing a coherence peak, indicative of UTe$_2$ being an unconventional superconductor. It was found that the temperature dependence of $1/T_1T$ in the SC state cannot be understood by a single SC gap behavior but can be explained by a two SC gap model. The Knight shift, proportional to the spin susceptibility, decreases below $T_c$, but the magnitude of the decrease is much smaller than the decrease expected in the spin-singlet pairing. Rather, the small Knight-shift decrease as well as the absence of the Pauli-depairing effect can be interpreted by the spin triplet scenario.
The thermal conductivity of the heavy-fermion superconductor CeCoIn_5 has been studied in a magnetic field rotating within the 2D planes. A clear fourfold symmetry of the thermal conductivity which is characteristic of a superconducting gap with node
s along the (+-pi,+-pi)-directions is resolved. The thermal conductivity measurement also reveals a first order transition at H_c2, indicating a Pauli limited superconducting state. These results indicate that the symmetry most likely belongs to d_{x^2-y^2}, implying that the anisotropic antiferromagnetic fluctuation is relevant to the superconductivity.
The physics of the crossover between weak-coupling Bardeen-Cooper-Schrieffer (BCS) and strong-coupling Bose-Einstein-condensate (BEC) limits gives a unified framework of quantum bound (superfluid) states of interacting fermions. This crossover has be
en studied in the ultracold atomic systems, but is extremely difficult to be realized for electrons in solids. Recently, the superconducting semimetal FeSe with a transition temperature $T_{rm c}=8.5$ K has been found to be deep inside the BCS-BEC crossover regime. Here we report experimental signatures of preformed Cooper pairing in FeSe below $T^*sim20$ K, whose energy scale is comparable to the Fermi energies. In stark contrast to usual superconductors, large nonlinear diamagnetism by far exceeding the standard Gaussian superconducting fluctuations is observed below $T^*sim20$ K, providing thermodynamic evidence for prevailing phase fluctuations of superconductivity. Nuclear magnetic resonance (NMR) and transport data give evidence of pseudogap formation at $sim T^*$. The multiband superconductivity along with electron-hole compensation in FeSe may highlight a novel aspect of the BCS-BEC crossover physics.