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تسجيل مستخدم جديدTiling of the five-fold surface of Al(70)Pd(21)Mn(9)
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The nature of the five-fold surface of Al(70)Pd(21)Mn(9) has been investigated using scanning tunneling microscopy. From high resolution images of the terraces, a tiling of the surface has been constructed using pentagonal prototiles. This tiling matches the bulk model of Boudard et. al. (J. Phys.: Cond. Matter 4, 10149, (1992)), which allows us to elucidate the atomic nature of the surface. Furthermore, it is consistent with a Penrose tiling T^*((P1)r) obtained from the geometric model based on the three-dimensional tiling T^*(2F). The results provide direct confirmation that the five-fold surface of i-Al-Pd-Mn is a termination of the bulk structure.
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The structure of the Al_{70}Pd_{21}Mn_{9} surface has been investigated using high resolution scanning tunnelling microscopy (STM). From two large five-fold terraces on the surface in a short decorated Fibonacci sequence, atomically resolved surfac
e images have been obtained. One of these terraces carries a rare local configuration in a form of a ring. The location of the corresponding sequence of terminations in the bulk model M of icosahedral i-AlPdMn based on the three-dimensional tiling T*(2F) of an F-phase has been estimated using this ring configuration and the requirement from the LEED work of Gierer et al. that the average atomic density of the terminations is 0.136 atoms per A^2. A termination contains two atomic plane layers separated by a vertical distance of 0.48 A. The position of the bulk terminations is fixed within the layers of Bergman polytopes in the model M: they are 4.08 A in the direction of the bulk from a surface of the most dense Bergman layers. From the coding windows of the top planes in terminations in M we conclude that a Penrose (P1) tiling is possible on almost all five-fold terraces. The shortest edge of the tiling P1, is either 4.8 A or 7.8 A. The experimentally derived tiling of the surface with the ring configuration has an edge-length of 8.0 +- 0.3 A and hence matches the minimal edge-length expected from the model.
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