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The 4.62 micron absorption band, observed along the line-of-sight towards various young stellar objects, is generally used as a qualitative indicator for energetic processing of interstellar ice mantles. This interpretation is based on the excellent fit with OCN-, which is readily formed by ultraviolet (UV) or ion-irradiation of ices containing H2O, CO and NH3. However, the assignment requires both qualitative and quantitative agreement in terms of the efficiency of formation as well as the formation of additional products. Here, we present the first quantitative results on the efficiency of laboratory formation of OCN- from ices composed of different combinations of H2O, CO, CH3OH, HNCO and NH3 by UV- and thermally-mediated solid state chemistry. Our results show large implications for the use of the 4.62 micron feature as a diagnostic for energetic ice-processing. UV-mediated formation of OCN- from H2O/CO/NH3 ice matrices falls short in reproducing the highest observed interstellar abundances. In this case, at most 2.7% OCN- is formed with respect to H2O under conditions that no longer apply to a molecular cloud environment. On the other hand, photoprocessing and in particular thermal processing of solid HNCO in the presence of NH3 are very efficient OCN- formation mechanisms, converting 60%--85% and ~100%, respectively of the original HNCO. We propose that OCN- is most likely formed thermally from HNCO given the ease and efficiency of this mechanism. Upper limits on solid HNCO and the inferred interstellar ice temperatures are in agreement with this scenario.
The formation of double and triple C-C bonds from the processing of pure c-C6H12 (cyclohexane) and mixed H2O:NH3:c-C6H12 (1:0.3:0.7) ices by highly-charged, and energetic ions (219 MeV O^{7+} and 632 MeV Ni^{24+}) is studied. The experiments simulate
Solid O2 has been proposed as a possible reservoir for oxygen in dense clouds through freeze-out processes. The aim of this work is to characterize quantitatively the physical processes that are involved in the desorption kinetics of CO-O2 ices by in
Population synthesis models of planetary systems developed during the last $sim$15 years could reproduce several of the observables of the exoplanet population, and also allowed to constrain planetary formation models. We present our planet formation
We present VLT/SINFONI near-infrared (NIR) integral field spectroscopy of six $z sim 0.2$ Lyman break galaxy analogs (LBAs), from which we detect HI, HeI, and [FeII] recombination lines, and multiple H$_2$ ro-vibrational lines in emission. Pa$alpha$
CO$_2$ ice is an important reservoir of carbon and oxygen in star and planet forming regions. Together with water and CO, CO$_2$ sets the physical and chemical characteristics of interstellar icy grain mantles, including desorption and diffusion ener