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Central stages in the evolution of rocky, potentially habitable planets may play out under atmospheric conditions with a large inventory of non-dilute condensable components. Variations in condensate retention and accompanying changes in local lapse rate may substantially affect planetary climate and surface conditions, but there is currently no general theory to effectively describe such atmospheres. In this article, expanding on the work by Li et al. (2018), we generalize the single-component moist pseudoadiabat derivation in Pierrehumbert (2010) to allow for multiple condensing components of arbitrary diluteness and retained condensate fraction. The introduction of a freely tunable retained condensate fraction allows for a flexible, self-consistent treatment of atmospheres with non-dilute condensable components. To test the pseudoadiabats capabilities for simulating a diverse range of climates, we apply the formula to planetary atmospheres with compositions, surface pressures, and temperatures representing important stages with condensable-rich atmospheres in the evolution of terrestrial planets: a magma ocean planet in a runaway greenhouse state; a post-impact, late veneer-analogue planet with a complex atmospheric composition; and an Archean Earth-like planet near the outer edge of the classical circumstellar habitable zone. We find that variations in the retention of multiple non-dilute condensable species can significantly affect the lapse rate and in turn outgoing radiation and the spectral signatures of planetary atmospheres. The presented formulation allows for a more comprehensive treatment of the climate evolution of rocky exoplanets and early Earth analogues.
New observing capabilities coming online over the next few years will provide opportunities for characterization of exoplanet atmospheres. However, clouds/hazes could be present in the atmospheres of many exoplanets, muting the amplitude of spectral
Sulfur gases significantly affect the photochemistry of planetary atmospheres in our Solar System, and are expected to be important components in exoplanet atmospheres. However, sulfur photochemistry in the context of exoplanets is poorly understood
Observations of exoplanet atmospheres have shown that aerosols, like in the Solar System, are common across a variety of temperatures and planet types. The formation and distribution of these aerosols are inextricably intertwined with the composition
High-resolution Doppler spectroscopy is a powerful tool for identifying molecular species in the atmospheres of both transiting and non-transiting exoplanets. Currently, such data is analysed using cross-correlation techniques to detect the Doppler s
A long-term goal of exoplanet studies is the identification and detection of biosignature gases. Beyond the most discussed biosignature gas O$_2$, only a handful of gases have been considered in detail. Here we evaluate phosphine (PH$_3$). On Earth,