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Two-dimensional (2D) Stiefel-Whitney insulator (SWI), which is characterized by the second Stiefel-Whitney class, is a new class of topological phases with zero Berry curvature. As a novel topological state, it has been well studied in theory but seldom realized in realistic materials. Here we propose that a large class of liganded Xenes, i.e., hydrogenated and halogenated 2D group-IV honeycomb lattices, are 2D SWIs. The nontrivial topology of liganded Xenes is identified by the bulk topological invariant and the existence of protected corner states. Moreover, the large and tunable band gap (up to 3.5 eV) of liganded Xenes will facilitate the experimental characterization of the 2D SWI phase. Our findings not only provide abundant realistic material candidates that are experimentally feasible, but also draw more fundamental research interest towards the topological physics associated with Stiefel-Whitney class in the absence of Berry curvature.
We predict a phase transition in freestanding monolayer Xenes from the semiconducting phase to the excitonic insulating (EI) phase can be induced by reducing an external electric field below some critical value which is unique to each material. The s
In this article, we review the recent progress in the study of topological phases in systems with space-time inversion symmetry $I_{text{ST}}$. $I_{text{ST}}$ is an anti-unitary symmetry which is local in momentum space and satisfies $I_{text{ST}}^2=
Two-dimensional (2D) materials have attracted much recent attention because they exhibit various distinct intrinsic properties/functionalities, which are, however, usually not interchangeable. Interestingly, here we propose a generic approach to conv
We have performed a computational screening of topological two-dimensional (2D) materials from the Computational 2D Materials Database (C2DB) employing density functional theory. A full textit{ab initio} scheme for calculating hybrid Wannier function
In crystal growth, surfactants are additive molecules used in dilute amount or as dense, permeable layers to control surface morphologies. Here, we investigate the properties of a strikingly different surfactant: a two-dimensional and covalent layer