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Spin-ordered electronic states in hydrogen-terminated zigzag nanographene give rise to magnetic quantum phenomena that have sparked renewed interest in carbon-based spintronics. Zigzag graphene nanoribbons (ZGNRs), quasi one-dimensional semiconducting strips of graphene featuring two parallel zigzag edges along the main axis of the ribbon, are predicted to host intrinsic electronic edge states that are ferromagnetically ordered along the edges of the ribbon and antiferromagnetically coupled across its width. Despite recent advances in the bottom-up synthesis of atomically-precise ZGNRs, their unique electronic structure has thus far been obscured from direct observations by the innate chemical reactivity of spin-ordered edge states. Here we present a general technique for passivating the chemically highly reactive spin-polarized edge states by introducing a superlattice of substitutional nitrogen-dopants along the edges of a ZGNR. First-principles GW calculations and scanning tunneling spectroscopy reveal a giant spin splitting of the low-lying nitrogen lone-pair flat bands by a large exchange field (~850 Tesla) induced by the spin-polarized ferromagnetically ordered edges of ZGNRs. Our findings directly corroborate the nature of the predicted emergent magnetic order in ZGNRs and provide a robust platform for their exploration and functional integration into nanoscale sensing and logic devices.
Carbon-based magnetic structures promise significantly longer coherence times than traditional magnetic materials, which is of fundamental importance for spintronic applications. An elegant way of achieving carbon-based magnetic moments is the design
We investigate electron and phonon transport through edge disordered zigzag graphene nanoribbons based on the same methodological tool of nonequilibrium Green functions. We show that edge disorder dramatically reduces phonon thermal transport while b
A central question in the field of graphene-related research is how graphene behaves when it is patterned at the nanometer scale with different edge geometries. Perhaps the most fundamental shape relevant to this question is the graphene nanoribbon (
We study the low energy spin excitations of zigzag graphene nanoribbons of varying width. We find their energy dispersion at small wave vector to be dominated by antiferromagnetic correlations between the ribbons edges, in accrodance with previous ca
We theoretically study electronic properties of a graphene sheet on xy plane in a spatially nonuniform magnetic field, $B = B_0 hat{z}$ in one domain and $B = B_1 hat{z}$ in the other domain, in the quantum Hall regime and in the low-energy limit. We