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Ne atoms with energies up to 3 keV are diffracted under grazing angles of incidence from a LiF(001) surface. For a small momentum component of the incident beam perpendicular to the surface, we observe an increase of the elastic rainbow angle together with a broadening of the inelastic scattering profile. We interpret these two effects as the refraction of the atomic wave in the attractive part of the surface potential. We use a fast, rigorous dynamical diffraction calculation to find a projectile-surface potential model that enables a quantitative reproduction of the experimental data for up to ten diffraction orders. This allows us to extract an attractive potential well depth of 10.4 meV. Our results set a benchmark for more refined surface potential models which include the weak Van der Waals region, a long-standing challenge in the study of atom-surface interactions.
Recent experiments have reported measurements of rainbow scattering features in the angular distributions of hyperthermal Ar colliding with LiF(001) [Kondo et al., J. Chem. Phys. 122, 244713 (2005)]. A semiclassical theory of atom-surface collisions
We theoretically address grazing incidence fast atom diffraction (GIFAD) for H atoms impinging on a LiF(001) surface. Our model combines a description of the H-LiF(001) interaction obtained from Density Functional Theory calculations with a semi-quan
Diffraction patterns produced by grazing scattering of fast atoms from insulator surfaces are used to examine the atom-surface interaction. The method is applied to He atoms colliding with a LiF(001) surface along axial crystallographic channels. The
We present a tree-tensor-network-state (TTNS) method study of the ionic-neutral curve crossing of LiF. For this ansatz, the long-range correlation deviates from the mean-field value polynomially with distance, thus for quantum chemical applications t
The rise of topology in condensed matter physics has generated strong interest in identifying novel quantum materials in which topological protection is driven by electronic correlations. Samarium hexaboride is a Kondo insulator for which it has been