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Very little experimental work has been done to explore the properties of photochemical hazes formed in atmospheres with very different compositions or temperatures than that of the outer solar system or of early Earth. With extrasolar planet discoveries now numbering thousands, this untapped phase space merits exploration. This study presents measured chemical properties of haze particles produced in laboratory analogues of exoplanet atmospheres. We used very high resolution mass spectrometry to measure the chemical components of solid particles produced in atmospheric chamber experiments. Many complex molecular species with general chemical formulas C$_w$H$_x$N$_y$O$_z$ were detected. We detect molecular formulas of prebiotic interest in the data, including those for the monosaccharide glyceraldehyde, a variety of amino acids and nucleotide bases, and several sugar derivatives. Additionally, the experimental exoplanetary haze analogues exhibit diverse solubility characteristics, which provide insight into the possibility of further chemical or physical alteration of photochemical hazes in super-Earth and mini-Neptune atmospheres. These exoplanet analogue particles can help us better understand chemical atmospheric processes and suggest a possible source of in situ atmospheric prebiotic chemistry on distant worlds.
The atmospheric composition of exoplanets with masses between 2 and 10 M$_oplus$ is poorly understood. In that regard, the sub-Neptune K2-18b, which is subject to Earth-like stellar irradiation, offers a valuable opportunity for the characterisation
HD3167 is a bright (V=8.9 mag) K0V star observed by the NASAs K2 space mission during its Campaign 8. It has been recently found to host two small transiting planets, namely, HD3167b, an ultra short period (0.96 d) super-Earth, and HD3167c, a mini-Ne
GJ1214b is thought to be either a mini-Neptune with a thick, hydrogen-rich atmosphere, or a planet with a composition dominated by water. In the case of a hydrogen-rich atmosphere, molecular absorption and scattering processes may result in detectabl
Precise atmospheric observations have been made for a growing sample of warm Neptunes. Here we investigate the correlations between these observations and a large number of system parameters to show that, at 95% confidence, the amplitude of a warm Ne
We detect Lyman $alpha$ absorption from the escaping atmosphere of HD 63433c, a $R=2.67 R_oplus$, $P=20.5$ d mini Neptune orbiting a young (440 Myr) solar analogue in the Ursa Major Moving Group. Using HST/STIS, we measure a transit depth of $11.1 pm