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تسجيل مستخدم جديدMagnetic correlations in subsystems of the misfit [Ca$_2$CoO$_3$]$_{0.62}$[CoO$_2$] cobaltate
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[Ca$_2$CoO$_3$]$_{0.62}$[CoO$_2$], a two dimensional misfit metallic compound, is famous for its rich phases accessed by temperature, $i.e.$ high temperature spin-state transition, metal-insulator transition (MIT) at intermediate temperature ($sim$ 100 K) and low temperature spin density wave (SDW). It enters into SDW phase below T$_{MIT}$ which becomes long range at 27 K. Information on the independent role of misfit layers (rocksalt/Ca$_2$CoO$_3$ & triangular/CoO$_2$) in these phases is scarce. By combining a set of complementary macroscopic (DC magnetization and resistivity) and microscopic (neutron diffraction and X-ray absorption fine structure spectroscopy) measurements on pure (CCO) and Tb substituted in the rocksalt layer of CCO (CCO1), magnetic correlations in both subsystems of this misfit compound are unraveled. CCO is found to exhibit glassiness, as well as exchange bias (EB) effects, while CCO1 does not exhibit glassiness, albeit it shows weaker EB effect. By combining local structure investigations from extended X-ray absorption fine structure (EXAFS) spectroscopy and neutron diffraction results on CCO, we confirm that the SDW arises in the CoO$_2$ layer. Our results show that the magnetocrystalline anisotropy associated with the rocksalt layer acts as a source of pinning, which is responsible for EB effect. Ferromagnetic clusters in the Ca$_2$CoO$_3$ affects SDW in CoO$_2$ and ultimately glassiness arises.
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Layered misfit cobaltate [Ca$_2$CoO$_3$]$_{0.62}$[CoO$_2$], which emerged as an important thermoelectric material~[A. C. Masset et al. Phys. Rev. B, 62, 166 (2000)], has been explored extensively in the last decade for the exact mechanism behind its
high Seebeck coefficient. Its complex crystal and electronic structures have inhibited consensus among such investigations. This situation has arisen mainly due to difficulties in accurate identification of the chemical state, spin state, and site symmetries in its two subsystems (rocksalt [Ca$_2$CoO$_3$] and triangular [CoO$_2$]). By employing resonant photoemission spectroscopy and x-ray absorption spectroscopy along with charge transfer multiplet simulations (at the Co ions), we have successfully identified the site symmetries, valencies and spin states of the Co in both layers. Our site-symmetry observations explain the experimental value of the high Seebeck coefficient and also confirm that the carriers hop within the rocksalt layer, which is in contrast to earlier reports where hopping within triangular CoO$_2$ layer has been held responsible for the large Seebeck coefficient.
Magnetism of a misfit layered cobaltite [Ca$_2$Co$_{4/3}$Cu$_{2/3}$O$_4$]$_x^{rm RS}$[CoO$_2$] ($x sim$ 0.62, RS denotes a rocksalt-type block) was investigated by a positive muon spin rotation and relaxation ($mu^+$SR) experiment. A transition to an
incommensurate ({sf IC}) spin density wave ({sf SDW}) state was found below 180 K (= $T_{rm C}^{rm on}$); and a clear oscillation due to a static internal magnetic field was observed below 140 K (= $T_{rm C}$). Furthermore, an anisotropic behavior of the zero-field $mu^+$SR experiment indicated that the {sf IC-SDW} propagates in the $a$-$b$ plane, with oscillating moments directed along the c axis. These results were quite similar to those for the related compound [Ca$_2$CoO$_3$]$_{0.62}^{rm RS}$[CoO$_2$], {sl i.e.}, Ca$_3$Co$_4$O$_9$. Since the {sf IC-SDW} field in [Ca$_2$Co$_{4/3}$Cu$_{2/3}$O$_4$]$_{0.62}^{rm RS}$[CoO$_2$] was approximately same to those in pure and doped [Ca$_2$CoO$_3$]$_{0.62}^{rm RS}$[CoO$_2$], it was concluded that the {sf IC-SDW} exist in the [CoO$_2$] planes.
The electric, magnetic, and thermal properties of three perovskite cobaltites with the same 30% hole doping and ferromagnetic ground state were investigated down to very low temperatures. With decreasing size of large cations, the ferromagnetic Curie
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The idea that surface effects may play an important role in suppressing $e_g$ Fermi surface pockets on Na$_x$CoO$_2$ $(0.333 le x le 0.75)$ has been frequently proposed to explain the discrepancy between LDA calculations (performed on the bulk compou
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