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The design of efficient electrocatalysts for electrochemical water splitting with minimal amount of precious metal is crucial to attain renewable and sustainable energy conversion. Here, we report the use of a network of CdSe branched colloidal nanocrystals, made of a CdSe core and eight CdSe pods (so-called octapods), able to host on their pods Pt particles, and thus catalyzing water splitting reactions. Thanks to the octapod shape, the resulting Pt-hosting network is mechanically trapped onto carbon nanotube buckypaper, providing mechanically flexible and binder-free electrodes. We found that such hierarchical configuration maximizes the mass activity and the utilization efficiency of Pt for the hydrogen evolution reaction (HER). At a potential of -0.15 V vs. reversible hydrogen electrode, the Pt/octapod network-based electrodes display a Pt mass activity on the HER of 166 A mg-1 and 42 A mg-1 in acidic and alkaline media, respectively. These values correspond to turnover frequencies of 168 s-1 and 42 s-1, respectively, which are in that order 14 and 21 times higher compared to commercially available Pt/C benchmarks. The strong chemical and mechanical interactions between the Pt and the octapod surface, along with pod-aided adhesion of the Pt/octapod network to the buckypaper, result in a long-term durability (>20 h) of the HER-activity in both media. These results experimentally prove that the exploitation of our network of branched nanocrystals hosting Pt particles can circumvent the durability issues of the catalysts while adopting either ultralow Pt loadings or benchmarking carbon-supported Pt nanocrystals. Our work opens up prospects for using porous networks made by branched nanocrystals as catalysts with ultralow amount of noble metals and controlled catalytic properties.
Two-dimensional (2D) boron monolayers have been successfully synthesized on silver substrate very recently. Their potential application is thus of great significance. In this work, we explore the possibility of boron monolayers (BMs) as electrocataly
Defined substoichiometric titanium oxides (Ti$_x$O$_{2x-1}$ with $3 < x < 10$) called Magneli phases have been investigated mostly for their unusual high conductivity and metal-like behavior. In photocatalysis, Magneli phase containing titania partic
Understanding the role of elastic strain in modifying catalytic reaction rates is crucial for catalyst design, but experimentally, this effect is often coupled with a ligand effect. To isolate the strain effect, we have investigated the influence of
Electrocatalytic hydrogen evolution reaction (HER) in alkaline media is a promising electrochemical energy conversion strategy. Ruthenium (Ru) is an efficient catalyst with a desirable cost for HER, however, the sluggish H2O dissociation process, due
In this work, we demonstrate that a well-established and facile ball milling approach using mixtures of commercial anatase nanoparticles and TiH2 introduces noble-metal-free photocatalytic H2 activity to titania. We characterize this synergistic effe