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The ever-increasing demand for high-capacity rechargeable batteries highlights the need for sensitive and accurate diagnostic technology for determining the state of a cell, for identifying and localizing defects, or for sensing capacity loss mechanisms. Here, we demonstrate the use of atomic magnetometry to map the weak induced magnetic fields around a Li-ion battery cell as a function of state of charge and upon introducing mechanical defects. These measurements provide maps of the magnetic susceptibility of the cell, which follow trends characteristic for the battery materials under study upon discharge. In addition, the measurements reveal hitherto unknown long time-scale transient internal current effects, which were particularly pronounced in the overdischarged regime. The diagnostic power of this technique is promising for the assessment of cells in research, quality control, or during operation, and could help uncover details of charge storage and failure processes in cells.
Solid state battery technology is motivated by the desire to deliver flexible power storage in a safe and efficient manner. The increasingly widespread use of batteries from mass-production facilities highlights the need for a rapid and sensitive dia
An improved spatial magnetometer using a spinor Bose-Einstein condensate of $^{87}$Rb atoms is realized utilizing newly developed two-polarization phase contrast imaging. The optical shot noise is suppressed by carefully choosing the probe parameters
The reversible heat in lithium-ion batteries (LIBs) due to entropy change is fundamentally important for understanding the chemical reactions in LIBs and developing proper thermal management strategies. However, the direct measurements of reversible
Atomic magnetometers are highly sensitive detectors of magnetic fields that monitor the evolution of the macroscopic magnetic moment of atomic vapors, and opening new applications in biological, physical, and chemical science. However, the performanc
Vector magnetometry was studied using the electromagnetically induced transparency (EIT) with linear $perp$ linear ($lin perp lin$) polarization of the probe and the pump beams in $^{87}Rb$ - $D_2$ transition. The dependence of the EIT on the directi