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تسجيل مستخدم جديدOn The Relation Between Equation-of-Motion Coupled-Cluster Theory and the GW Approximation
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We discuss the analytic and diagrammatic structure of ionization potential (IP) and electron affinity (EA) equation-of-motion coupled-cluster (EOM-CC) theory, in order to put it on equal footing with the prevalent $GW$ approximation. The comparison is most straightforward for the time-ordered one-particle Greens function, and we show that the Greens function calculated by EOM-CC with single and double excitations (EOM-CCSD) includes fewer ring diagrams at higher order than does the $GW$ approximation, due to the formers unbalanced treatment of time-ordering. However, the EOM-CCSD Greens function contains a large number of vertex corrections, including ladder diagrams, mixed ring-ladder diagrams, and exchange diagrams. By including triple excitations, the EOM-CCSDT Greens function includes all diagrams contained in the $GW$ approximation, along with many high-order vertex corrections. In the same language, we discuss a number of common approximations to the EOM-CCSD equations, many of which can be classified as elimination of diagrams. Finally, we present numerical results by calculating the principal charged excitations energies of the molecules contained in the so-called $GW$100 test set [J. Chem. Theory Comput. 2015, 11, 5665-5687]. We argue that (in molecules) exchange is as important as screening, advocating for a Hartree-Fock reference and second-order exchange in the self-energy.
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