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We extend the theory of dipole moments in crystalline insulators to higher multipole moments. In this paper, we expand in great detail the theory presented in Ref. 1, and extend it to cover associated topological pumping phenomena, and a novel class of 3D insulator with chiral hinge states. In quantum-mechanical crystalline insulators, higher multipole bulk moments manifest themselves by the presence of boundary-localized moments of lower dimension, in exact correspondence with the electromagnetic theory of classical continuous dielectrics. In the presence of certain symmetries, these moments are quantized, and their boundary signatures are fractionalized. These multipole moments then correspond to new SPT phases. The topological structure of these phases is described by nested Wilson loops, which reflect the bulk-boundary correspondence in a way that makes evident a hierarchical classification of the multipole moments. Just as a varying dipole generates charge pumping, a varying quadrupole generates dipole pumping, and a varying octupole generates quadrupole pumping. For non-trivial adiabatic cycles, the transport of these moments is quantized. An analysis of these interconnected phenomena leads to the conclusion that a new kind of Chern-type insulator exists, which has chiral, hinge-localized modes in 3D. We provide the minimal models for the quantized multipole moments, the non-trivial pumping processes and the hinge Chern insulator, and describe the topological invariants that protect them.
In this article we extend the celebrated Berry-phase formulation of electric polarization in crystals to higher electric multipole moments. We determine the necessary conditions under which, and minimal models in which, the quadrupole and octupole mo
The bulk-boundary correspondence, which links a bulk topological property of a material to the existence of robust boundary states, is a hallmark of topological insulators. However, in crystalline topological materials the presence of boundary states
The modern theory of electric polarization has recently been extended to higher multipole moments, such as quadrupole and octupole moments. The higher electric multipole insulators are essentially topological crystalline phases protected by underlyin
We study the properties of a family of anti-pervoskite materials, which are topological crystalline insulators with an insulating bulk but a conducting surface. Using ab-initio DFT calculations, we investigate the bulk and surface topology and show t
Topological photonics provides a fundamental framework for robust manipulation of light, including directional transport and localization with built-in immunity to disorder. Combined with an optical gain, active topological cavities hold special prom