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تسجيل مستخدم جديدStrong magnetic frustration in Y$_{3}$Cu$_{9}$(OH)$_{19}$Cl$_{8}$: a distorted kagome antiferromagnet
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We present the crystal structure and magnetic properties of Y$_{3}$Cu$_{9}$(OH)$_{19}$Cl$_{8}$, a stoichiometric frustrated quantum spin system with slightly distorted kagome layers. Single crystals of Y$_{3}$Cu$_{9}$(OH)$_{19}$Cl$_{8}$ were grown under hydrothermal conditions. The structure was determined from single crystal X-ray diffraction and confirmed by neutron powder diffraction. The observed structure reveals two different Cu-positions leading to a slightly distored kagome layer in contrast to the closely related YCu$_{3}$(OH)$_{6}$Cl$_{3}$. Curie-Weiss behavior at high-temperatures with a Weiss-temperature $theta_{W}$ of the order of $-100$ K, shows a large dominant antiferromagnetic coupling within the kagome planes. Specific-heat and magnetization measurements on single crystals reveal an antiferromagnetic transition at T$_{N}=2.2$ K indicating a pronounced frustration parameter of $theta_{W}/T_{N}approx50$. Optical transmission experiments on powder samples and single crystals confirm the structural findings. Specific-heat measurements on YCu$_{3}$(OH)$_{6}$Cl$_{3}$ down to 0.4 K confirm the proposed quantum spin-liquid state of that system. Therefore, the two Y-Cu-OH-Cl compounds present a unique setting to investigate closely related structures with a spin-liquid state and a strongly frustrated AFM ordered state, by slightly releasing the frustration in a kagome lattice.
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Experimental studies of high-purity kagome-lattice antiferromagnets (KAFM) are of great importance in attempting to better understand the predicted enigmatic quantum spin-liquid ground state of the KAFM model. However, realizations of this model can
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