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We present a general parameter study, in which the abundance of interstellar argonium (ArH$^+$) is predicted using a model for the physics and chemistry of diffuse interstellar gas clouds. Results have been obtained as a function of UV radiation field, cosmic-ray ionization rate, and cloud extinction. No single set of cloud parameters provides an acceptable fit to the typical ArH$^+$, OH$^+$ and $rm H_2O^+$ abundances observed in diffuse clouds within the Galactic disk. Instead, the observed abundances suggest that ArH$^+$ resides primarily in a separate population of small clouds of total visual extinction of at most 0.02 mag per cloud, within which the column-averaged molecular fraction is in the range $10^{-5} - 10^{-2}$, while OH$^+$ and $rm H_2O^+$ reside primarily in somewhat larger clouds with a column-averaged molecular fraction $sim 0.2$. This analysis confirms our previous suggestion that the argonium molecular ion is a unique tracer of almost purely atomic gas.
We study the behavior of eight diffuse interstellar bands (DIBs) in different interstellar environments, as characterized by the fraction of hydrogen in molecular form [$f$(H$_2$)], with comparisons to the corresponding behavior of various known atom
We describe the assignment of a previously unidentified interstellar absorption line to ArH$^+$ and discuss its relevance in the context of hydride absorption in diffuse gas with a low H$_2$ fraction. The column densities along several lines of sight
The 1-50 GHz GBT PRIMOS data contains ~50 molecular absorption lines observed in diffuse and translucent clouds located in the Galactic Center, Bar, and spiral arms in the line-of-sight to Sgr B2(N). We measure the column densities and estimate abund
One of the surprises of the Herschel mission was the detection of ArH+ towards the Crab Nebula in emission and in absorption towards strong Galactic background sources. Although these detections were limited to the first quadrant of the Galaxy, the e
We report the detection of absorption by interstellar hydroxyl cations and water cations, along the sight-line to the bright continuum source W49N. We have used Herschels HIFI instrument, in dual beam switch mode, to observe the 972 GHz N = 1 - 0 tra