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تسجيل مستخدم جديدMagnetic State of the Geometrically Frustrated Quasi-One-Dimensional Spin System Cu$_3$Mo$_2$O$_9$ Studied by Thermal Conductivity
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We have measured the thermal conductivity of the geometrically frustrated quasi-onedimensional spin system Cu$_3$Mo$_2$O$_9$ in magnetic fields. A contribution of the thermal conductivity due to spins has been observed in the thermal conductivity along the spin chains. The thermal conductivity due to phonons, $kappa_{rm phonon}$, has been found to decrease by the application of a magnetic field, which has been explained as being due to the reduction in the spin gap originating from the spin-singlet dimers. Moreover, it has been found that $kappa_{rm phonon}$ increases with increasing field in high fields above ~7 T at low temperatures. This suggests the existence of a novel field-induced spin state and is discussed in terms of the possible spin-chirality ordering in a frustrated Mott insulator.
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We have measured the thermal conductivity along the [101] direction, kappa_[101]_, along the [10-1] direction, kappa_[10-1]_, and along the b-axis, kappa_b_, of the quasi one-dimensional S=1/2 spin system Sr_2_V_3_O_9_ in magnetic fields up to 14 T,
in order to find the thermal conductivity due to spinons and to clarify whether the spin-chains run along the [101] or [10-1] direction. It has been found that both kappa_[101]_, kappa_[10-1]_ and kappa_b_ show one peak around 10 K in zero field and that the magnitude of kappa_[10-1]_ is larger than those of kappa_[101]_ and kappa_b_. By the application of magnetic field along the heat current, the peak of kappa_[10-1]_ is markedly suppressed, while the peaks of kappa_[101]_ and kappa_b_ little change. These results indicate that there is a large contribution of spinons to kappa_[10-1]_ and suggest that the spin-chains run along the [10-1] direction.
LiZn$_2$Mo$_3$O$_8$ has been proposed to contain $S~=~1/2$ Mo$_3$O$_{13}$ magnetic clusters arranged on a triangular lattice with antiferromagnetic nearest-neighbor interactions. Here, microwave and terahertz electron spin resonance (ESR), $^7$Li nuc
lear magnetic resonance (NMR), and muon spin rotation ($mu textrm{SR}$) spectroscopies are used to characterize the local magnetic properties of LiZn$_2$Mo$_3$O$_8$. These results show the magnetism in LiZn$_2$Mo$_3$O$_8$ arises from a single isotropic $S~=~1/2$ electron per cluster and that there is no static long-range magnetic ordering down to $T~=~0.07,textrm{K}$. Further, there is evidence of gapless spin excitations with spin fluctuations slowing down as the temperature is lowered. These data indicate strong spin correlations which, together with previous data, suggest a low-temperature resonating valence-bond state in LiZn$_2$Mo$_3$O$_8$.
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hree-dimensional magnetic lattice are extremely rare since both larger spin and higher dimension tend to suppress quantum fluctuations. In this work, we offer a new strategy to achieve 3-D QSL with high spin by utilizing two types of transition metal ions, both are magnetically active but located at crystallographically inequivalent positions. We design a 3-D magnetic system Ba$_3$NiIr$_2$O$_9$ consisting of interconnected corner shared NiO$_6$ octahedra and face shared Ir$_2$O$_9$ dimer, both having triangular arrangements in textit{a-b} plane. X-ray absorption spectroscopy measurements confirm the presence of Ni$^{2+}$ ($S$=1). Our detailed thermodynamic and magnetic measurements reveal that this compound is a realization of gapless QSL state down to at least 100 mK. Ab-initio calculations find a strong magnetic exchange between Ir and Ni sublattices and in-plane antiferromagnetic coupling between the dimers, resulting in dynamically fluctuating magnetic moments on both the Ir and Ni sublattice.
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