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We study hole, electron and exciton transport in a charge transfer system in the presence of underdamped vibrational motion. We analyze the signature of these processes in the linear and third-, and fifth-order nonlinear electronic spectra. Calculations are performed with a numerically exact hierarchical equations of motion method for an underdamped Brownian oscillator spectral density. We find that combining electron, hole and exciton transfer can lead to non-trivial spectra with more structure than with excitonic coupling alone. Traces taken during the waiting time of a two-dimensional spectrum are dominated by vibrational motion and do not reflect the electron, hole, and exciton dynamics directly. We find that the fifth-order nonlinear response is particularly sensitive to the charge transfer process. While third-order 2D spectroscopy detects the correlation between two coherences, fifth-order 2D spectroscopy (2D population spectroscopy) is here designed to detect correlations between the excited states during two different time periods.
We report nonlinear vibration localisation in a system of two symmetric weakly coupled nonlinear oscillators. A two degree-of-freedom model with piecewise linear stiffness shows bifurcations to localised solutions. An experimental investigation emplo
We investigate photoinduced proton-coupled electron transfer (PI-PCET) reaction through a recently devel- oped quasi-diabatic (QD) quantum dynamics propagation scheme. This scheme enables interfacing accurate diabatic-based quantum dynamics approache
An experimental setup of three coupled $mathcal{PT}$-symmetric wave guides showing the characteristics of a third-order exceptional point (EP3) has been investigated in an idealized model of three delta-functions wave guides in W.~D. Heiss and G.~Wun
We investigate the quantum dynamics of energy and charge transfer in a wheel-shaped artificial photosynthetic antenna-reaction center complex.This complex consists of six light-harvesting chromophores and an electron-acceptor fullerene. To describe q
When the nonlinearity of nanomechanical resonator is not negligible, the quantum decoherence of charge qubit is studied analytically. Using nonlinear Jaynes-Cummings model, one explores the possibility of being quantum data bus for nonlinear nanomech