اشترك بالحزمة الذهبية واحصل على وصول غير محدود شمرا أكاديميا
تسجيل مستخدم جديدCritical wetting, first-order wetting and prewetting phase transitions in binary mixtures of Bose-Einstein condensates
254
0
0.0
(
0
)
اسأل ChatGPT حول البحث
ﻻ يوجد ملخص باللغة العربية
An ultralow-temperature binary mixture of Bose-Einstein condensates adsorbed at an optical wall can undergo a wetting phase transition in which one of the species excludes the other from contact with the wall. Interestingly, while hard-wall boundary conditions entail the wetting transition to be of first order, using Gross-Pitaevskii theory we show that first-order wetting as well as critical wetting can occur when a realistic exponential optical wall potential (evanescent wave) with a finite turn-on length $lambda$ is assumed. The relevant surface excess energies are computed in an expansion in $lambda/xi_i$, where $xi_i$ is the healing length of condensate $i$. Experimentally, the wetting transition may best be approached by varying the interspecies scattering length $a_{12}$ using Feshbach resonances. In the hard-wall limit, $lambda rightarrow 0$, exact results are derived for the prewetting and first-order wetting phase boundaries.
قيم البحث
اقرأ أيضاً
A mean-field theory is presented which describes the basic observations of recent experiments revealing rich wetting behaviour of n-alkane/methanol mixtures at the liquid-vapour interface. The theory, qualitative and in part heuristic, is based on a
microscopic lattice-gas model from which a Cahn-Landau approach is distilled. Besides the physics associated with the short-range components of the intermolecular interactions, effects of the long-range tails of the net van der Waals forces between interfaces are also taken into account. Including weak long-range forces which favour wetting in the theory does not visibly alter the critical wetting transition for the nonane/methanol mixture, in contrast with the generic expectation of first-order wetting for such systems, but in good agreement with experiment. For decane/methanol weak long-range forces bring the transition very close to the prewetting critical point, leading to an adsorption behaviour closely reminiscent of short-range tricritical wetting, observed experimentally for alkane chain length between 9.6 and 10. Finally, for undecane/methanol the transition is clearly of first order. First-order wetting is also seen in the experiment.
In living cells, protein-rich condensates can wet the cell membrane and surfaces of membrane-bound organelles. Interestingly, many phase-separating proteins also bind to membranes leading to a molecular layer of bound molecules. Here we investigate h
ow binding to membranes affects surface phase transitions such as wetting and prewetting. We derive a thermodynamic theory for a three-dimensional bulk in the presence of a two-dimensional, flat membrane. Above the saturation concentration, we find that membrane binding facilitates complete wetting and lowers the wetting angle. Moreover, below the saturation concentration, binding facilitates the formation of a thick layer at the membrane and thereby shifts the prewetting phase transition far below the saturation concentration. The distinction between bound and unbound molecules near the surface leads to a large variety of prewetted states. Our work suggests that surface phase transitions combined with molecular binding represent a versatile mechanism to control the formation of protein-rich domains at intra-cellular surfaces.
Cold atom developments suggest the prospect of measuring scaling properties and long-range fluctuations of continuous phase transitions at zero-temperature. We discuss the conditions for characterizing the phase separation of Bose-Einstein condensate
s of boson atoms in two distinct hyperfine spin states. The mean-field description breaks down as the system approaches the transition from the miscible side. An effective spin description clarifies the ferromagnetic nature of the transition. We show that a difference in the scattering lengths for the bosons in the same spin state leads to an effective internal magnetic field. The conditions at which the internal magnetic field vanishes (i.e., equal values of the like-boson scattering lengths) is a special point. We show that the long range density fluctuations are suppressed near that point while the effective spin exhibits the long-range fluctuations that characterize critical points. The zero-temperature system exhibits critical opalescence with respect to long wavelength waves of impurity atoms that interact with the bosons in a spin-dependent manner.
The profile of a critical hole in an undercooled wetting layer is determined by the saddle-point equation of a standard interface Hamiltonian supported by convenient boundary conditions. It is shown that this saddle-point equation can be mapped onto
an autonomous dynamical system in a three-dimensional phase space. The corresponding flux has a polynomial form and in general displays four fixed points, each with different stability properties. On the basis of this picture we derive the thermodynamic behaviour of critical holes in three different nucleation regimes of the phase diagram.
Interfacial profiles and interfacial tensions of phase-separated binary mixtures of Bose-Einstein condensates are studied theoretically. The two condensates are characterized by their respective healing lengths $xi_1$ and $xi_2$ and by the inter-spec
ies repulsive interaction $K$. An exact solution to the Gross-Pitaevskii (GP) equations is obtained for the special case $xi_2/xi_1 = 1/2$ and $K = 3/2$. Furthermore, applying a double-parabola approximation (DPA) to the energy density featured in GP theory allows us to define a DPA model, which is much simpler to handle than GP theory but nevertheless still captures the main physics. In particular, a compact analytic expression for the interfacial tension is derived that is useful for all $xi_1, xi_2$ and $K$. An application to wetting phenomena is presented for condensates adsorbed at an optical wall. The wetting phase boundary obtained within the DPA model nearly coincides with the exact one in GP theory.
سجل دخول لتتمكن من نشر تعليقات
التعليقات
جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
