ترغب بنشر مسار تعليمي؟ اضغط هنا

Gaps and pseudo-gaps at the Mott quantum Critical point in the perovskite rare earth nickelates

148   0   0.0 ( 0 )
 نشر من قبل Silas Allen
 تاريخ النشر 2014
  مجال البحث فيزياء
والبحث باللغة English




اسأل ChatGPT حول البحث

We report on tunneling measurements that reveal for the first time the evolution of the quasi-particle state density across the bandwidth controlled Mott metal to insulator transition in the rare earth perovskite nickelates. In this, a canonical class of transition metal oxides, we study in particular two materials close to the T=0 metal-insulator transition: NdNiO3 , an antiferromagnetic insulator, and LaNiO3, a correlated metal. We measure a sharp gap in NdNiO3, which has an insulating ground state, of ~ 30 meV. Remarkably, metallic LaNiO3 exhibits a pseudogap of the same order that presages the metal insulator transition. The smallness of both the gap and pseudogap suggests they arise from a common origin: proximity to a quantum critical point at or near the T=0 metal-insulator transition. It also supports theoretical models of the quantum phase transition in terms of spin and charge instabilities of an itinerant Fermi surface.

قيم البحث

اقرأ أيضاً

The metal-insulator transition (MIT) remains among the most thoroughly studied phenomena in solid state physics, but the complexity of the phenomena, which usually involves cooperation of many degrees of freedom including orbitals, fluctuating local moments, magnetism, and the crystal structure, have resisted predictive ab-initio treatment. Here we develop ab-initio theoretical method for correlated electron materials, based on Dynamical Mean Field Theory, which can predict the change of the crystal structure across the MIT at finite temperature. This allows us to study the coupling between electronic, magnetic and orbital degrees of freedom with the crystal structure across the MIT in rare-earth nickelates. We predict the free energy profile of the competing states, and the theoretical magnetic ground state configuration, which is in agreement with neutron scattering data, but is different from the magnetic models proposed before. The resonant elastic X-ray response at the K-edge, which was argued to be a direct probe of the charge order, is theoretically modelled within the Dynamical Mean Field Theory, including the core-hole interaction. We show that the line-shape of the measured resonant elastic X-ray response can be explained with the site-selective Mott scenario without real charge order on Ni sites.
We address the quantum-critical behavior of a two-dimensional itinerant ferromagnetic systems described by a spin-fermion model in which fermions interact with close to critical bosonic modes. We consider Heisenberg ferromagnets, Ising ferromagnets, and the Ising nematic transition. Mean-field theory close to the quantum critical point predicts a superconducting gap with spin-triplet symmetry for the ferromagnetic systems and a singlet gap for the nematic scenario. Studying fluctuations in this ordered phase using a nonlinear sigma model, we find that these fluctuations are not suppressed by any small parameter. As a result, we find that a superconducting quasi-long-range order is still possible in the Ising-like models but long-range order is destroyed in Heisenberg ferromagnets.
We show that charge ordering (more precisely, two-sublattice bond disproportionation) in the rare earth nickelate perovskites is intimately related to a negative charge transfer energy. By adding an additional potential on the Ni d states we are able to vary the charge tranfer energy and compute relaxed structures within an ab-initio framework. We show that the difference in Ni-O bond lengths and the value of the ordered state magnetic moment correlate with the charge transfer energy and that the transition to the bond-disproportionated state occurs when the effective charge transfer energy becomes negative.
A substantial energy gap of charge excitations induced by strong correlations is the characteristic feature of Mott insulators. We study how the Mott gap is affected by the long-range antiferromagnetic order. Our key finding is that the Mott gap is e nhanced by the magnetic ordering: a magnetic blue-shift (MBS) occurs. We establish this important and general effect in a three-dimensional Hubbard model, the paradigm for strongly correlated systems, without any spin-orbit term. The MBS is thus of exchange origin and can increase the Mott gap by approximately $70%$ as the temperature decreases from the ordering temperature to zero. The coupling between spin and charge degrees of freedom bears the potential to enable spin-to-charge conversion in Mott systems on extreme time-scales determined by the exchange only, since spin-orbit mediated transfer of angular momentum is not involved in the process. In view of spintronic and magnonic applications, we show that the magnetic contribution to the band-gap blue-shift observed in the optical conductivity of $alpha$-MnTe is correctly interpreted as the MBS of a Mott gap.
Whilst electron correlations were previously recognized to trigger beyond conventional direct current (DC) electronic transportations (e.g. metal-to-insulator transitions, bad metal, thermistors), their respective influences to the alternation curren t (AC) transport are largely overlooked. Herein, we demonstrate active regulations in the electronic functionalities of d-band correlated rare-earth nickelate (ReNiO3) thin films, by simply utilizing their electronic responses to AC-frequencies (fAC). Assisted by temperature dependent near edge X-ray absorption fine structure analysis, we discovered positive temperature dependences in Coulomb viscosity of ReNiO3 that moderates their AC impedance. Distinguished crosslinking among R(Real)-fAC measured in nearby temperatures is observed that differs to conventional oxides. It enables active adjustability in correlated transports of ReNiO3, among NTCR-, TDelta- and PTCR- thermistors, via fAC from the electronic perspective without varying materials or device structures. The TDelta-fAC relationship can be further widely adjusted via Re composition and interfacial strains. The AC-frequency sensitivity discovered in ReNiO3 brings in a new freedom to regulating and switching the device working states beyond the present semiconductor technologies. It opens a new paradigm for enriching novel electronic applications catering automatic transmission or artificial intelligence in sensing temperatures and frequencies.
التعليقات
جاري جلب التعليقات جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
mircosoft-partner

هل ترغب بارسال اشعارات عن اخر التحديثات في شمرا-اكاديميا